Entropy production and the Ostwald step rule

1988 ◽  
Vol 92 (1) ◽  
pp. 226-227 ◽  
Author(s):  
William H. Casey
Keyword(s):  
Entropy Production ◽  
Ostwald Step Rule

Complete monotonicity of entropy production in chemical reaction

1981 ◽  
Vol 46 (2) ◽  
pp. 452-456
Author(s):  
Milan Šolc
Keyword(s):  
Entropy Production ◽  
Equilibrium Constant ◽  
Chemical Reaction ◽  
Relative Entropy ◽  
Order Reaction ◽  
Complete Monotonicity ◽  
First Order Reaction ◽  
First Order ◽  
Completely Monotonic ◽  
Derivatives Of

The successive time derivatives of relative entropy and entropy production for a system with a reversible first-order reaction alternate in sign. It is proved that the relative entropy for reactions with an equilibrium constant smaller than or equal to one is completely monotonic in the whole definition interval, and for reactions with an equilibrium constant larger than one this function is completely monotonic at the beginning of the reaction and near to equilibrium.

Optimal hydraulic design of an ultra-low specific speed centrifugal pump based on the local entropy production theory

2019 ◽  
Vol 233 (6) ◽  
pp. 715-726 ◽  
Author(s):  
Hucan Hou ◽  
Yongxue Zhang ◽  
Xin Zhou ◽  
Zhitao Zuo ◽  
Haisheng Chen
Keyword(s):  
Entropy Production ◽  
Centrifugal Pump ◽  
Orthogonal Design ◽  
High Energy ◽  
Geometrical Parameters ◽  
Production Theory ◽  
Local Entropy ◽  
Hydraulic Design ◽  
Low Specific Speed ◽  
Specific Speed

The ultra-low specific speed centrifugal pump has been widely applied in aerospace engineering, metallurgy, and other industrial fields. However, its hydraulic design lacks specialized theory and method. Moreover, the impeller and volute are designed separately without considering their coupling effect. Therefore, the optimal design is proposed in this study based on the local entropy production theory. Four geometrical parameters are selected to establish orthogonal design schemes including blade outlet setting angle, wrapping angle volute inlet width, and throat area. Subsequently, a 3D steady flow with Reynolds stress turbulent model and energy equation model is numerically conducted and the entropy production is calculated by a user-defined function code. The range analysis is made to identify the optimal scheme indicating that the combination of local entropy production and orthogonal design is feasible on pump optimization. The optimal pump is visibly improved with an increase of 1.08% in efficiency. Entropy production is decreased by 16.75% and 6.03% in impeller and volute, respectively. High energy loss areas are captured and explained in terms of helical vortex and wall friction, and the turbulent and wall entropy production are respectively reduced by 3.82% and 14.34% for the total pump.

scholarly journals Stochastic Discrete Time Crystals: Entropy Production and Subharmonic Synchronization

2021 ◽  
Vol 126 (2) ◽  
Author(s):  
Lukas Oberreiter ◽  
Udo Seifert ◽  
Andre C. Barato
Keyword(s):  
Entropy Production ◽  
Discrete Time ◽  
Time Crystals
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