scholarly journals Mechanism of the reaction of nitric oxide, ammonia, and oxygen over vanadia catalysts. 2. Isotopic transient studies with oxygen-18 and nitrogen-15

1987 ◽  
Vol 91 (27) ◽  
pp. 6633-6638 ◽  
Author(s):  
Frans J. J. G. Janssen ◽  
Frans M. G. Van den Kerkhof ◽  
Hans. Bosch ◽  
Julian R. H. Ross
Keyword(s):  
Nitric Oxide ◽  
Mechanism Of The Reaction ◽  
Vanadia Catalysts

Nitrogen-15 tracer investigation of the mechanism of the reaction of nitric oxide with ammonia on vanadium oxide catalysts

1982 ◽  
Vol 86 (15) ◽  
pp. 2945-2950 ◽  
Author(s):  
Akira Miyamoto ◽  
Kan Kobayashi ◽  
Makoto Inomata ◽  
Yuichi Murakami
Keyword(s):  
Nitric Oxide ◽  
Vanadium Oxide ◽  
Oxide Catalysts ◽  
Mechanism Of The Reaction

Stabile und instabile Produkte bei der Reaktion von 2.2-Diphenyl-1,2-dihydrochinolinnitroxid-Radikalen mit Stickstoffmonoxid / Stable and Unstable Products on the Reaction of 2.2-Diphenyl-1,2-dihydroquinolinenitroxide Radicals with Nitric Oxide

1994 ◽  
Vol 49 (8) ◽  
pp. 1041-1050 ◽  
Author(s):  
Horst Weber ◽  
Andreas Grzesiok ◽  
Reiner Sustmann ◽  
Hans-Gert Korth
Keyword(s):  
Nitric Oxide ◽  
Nitro Compounds ◽  
Nitroso Compounds ◽  
Mechanism Of The Reaction

The stable 2,2-diphenyl-1,2-dihydroquinolinenitroxide radicals 1 react with nitric oxide (NO) to form the stable nitro compounds 2 and 3 as main products. The stable dinitro compounds 6 and 1,2-dihydroquinolines 7 are formed in minor yield as side-products accom­panied with the unstable N-nitroso compounds 4 and 5, which further decompose to form the stable products mentioned above. The proposed mechanism of the reaction is discussed in terms of homolytical processes and is supported by PM 3 calculations.

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