The addition and dissociation reaction atomic hydrogen + carbon monoxide .dblharw. oxomethyl. 2. Experimental studies and comparison with theory

1987 ◽  
Vol 91 (20) ◽  
pp. 5325-5332 ◽  
Author(s):  
Raimo S. Timonen ◽  
Emil. Ratajczak ◽  
David. Gutman ◽  
Albert F. Wagner
Keyword(s):  
Carbon Monoxide ◽  
Atomic Hydrogen ◽  
Experimental Studies ◽  
Dissociation Reaction

scholarly journals Recent Advances in ZnO-Based Carbon Monoxide Sensors: Role of Doping

Sensors ◽  
2021 ◽  
Vol 21 (13) ◽  
pp. 4425
Author(s):  
Ana María Pineda-Reyes ◽  
María R. Herrera-Rivera ◽  
Hugo Rojas-Chávez ◽  
Heriberto Cruz-Martínez ◽  
Dora I. Medina
Keyword(s):  
Carbon Monoxide ◽  
High Performance ◽  
Gas Sensing ◽  
Experimental Studies ◽  
Electrical Performance ◽  
Long Term Stability ◽  
Sensing Applications ◽  
Recent Advances ◽  
Sensitivity And Selectivity ◽  
Doped Zno

Monitoring and detecting carbon monoxide (CO) are critical because this gas is toxic and harmful to the ecosystem. In this respect, designing high-performance gas sensors for CO detection is necessary. Zinc oxide-based materials are promising for use as CO sensors, owing to their good sensing response, electrical performance, cost-effectiveness, long-term stability, low power consumption, ease of manufacturing, chemical stability, and non-toxicity. Nevertheless, further progress in gas sensing requires improving the selectivity and sensitivity, and lowering the operating temperature. Recently, different strategies have been implemented to improve the sensitivity and selectivity of ZnO to CO, highlighting the doping of ZnO. Many studies concluded that doped ZnO demonstrates better sensing properties than those of undoped ZnO in detecting CO. Therefore, in this review, we analyze and discuss, in detail, the recent advances in doped ZnO for CO sensing applications. First, experimental studies on ZnO doped with transition metals, boron group elements, and alkaline earth metals as CO sensors are comprehensively reviewed. We then focused on analyzing theoretical and combined experimental–theoretical studies. Finally, we present the conclusions and some perspectives for future investigations in the context of advancements in CO sensing using doped ZnO, which include room-temperature gas sensing.

scholarly journals The study on decreasing of nitrogen oxides emission carried out on DKVR 10-13 industrial heating boilers

2018 ◽  
Vol 44 ◽  
pp. 00056 ◽  
Author(s):  
Sylwia Janta-Lipińska ◽  
Alexander Shkarovskiy
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxides ◽  
Experimental Studies ◽  
Steam Injection ◽  
Reference Level ◽  
Optimal Parameters ◽  
End Caps ◽  
Atmosphere Pollution ◽  
Industrial Heating ◽  
Study Plan

Nitrogen oxides are considered to be much more toxic than, for example, carbon monoxide. For this reason, the Authors developed and implemented a method for decrease of NOX emission into the atmosphere from DKVR 10-13 boilers. As an effective method for boilers propose injection of steam into the combustion zone. After series of experimental studies an optimal design of the head for steam injection was developed, according to the proprietary technology. The injector head was kept unchanged while the spraying end caps were modified (Fig. 2). Three levels of possible impact of emissions from boiler on the atmosphere pollution were taken into account during studies. After the analysis, it was assumed that the level of the real maximum emission should be taken as the reference level in relation to which the decrease of NOX emission should be determined. The results obtained by the Authors calculated into mass emission and as objective values of nitrogen oxides concentration calculated into α = 1 (Figures 3 and 4). Realization of the study plan, assumed by the Authors, allowed to determine the optimal parameters of the NOx emission decrease method, assuming the expected 30% level of emission decrease at a limited consumption of injected.

Oscillations, glow and ignition in carbon monoxide oxidation in an open system. I. Experimental studies of the ignition diagram and the effects of added hydrogen

1985 ◽  
Vol 397 (1812) ◽  
pp. 21-44 ◽  
Keyword(s):  
Carbon Monoxide ◽  
Open System ◽  
Reaction Rate ◽  
Experimental Studies ◽  
Reaction Rates ◽  
Step Change ◽  
Stable Node ◽  
Stationary States ◽  
Show Evidence ◽  
Oxidation Of Carbon Monoxide

The oxidation of carbon monoxide in equimolar mixtures (CO + O 2 ) has been studied in a well-stirred open system (0.5 dm 3 ) at vessel temperatures in the range 700-840 K, and reactant pressures up to 100 Torr ( ca . 13.3 kPa) at a mean residence time of 8.5 s. Stationary states are established and oscillatory states sustained indefinitely in this system. The effect of small quantities of added hydrogen is studied by a carefully controlled, continuous supplement to the principal reactants. Four different modes of reaction (I-IV) have been characterized, and conditions for their occurrence mapped on a reactant pressure-vessel temperature ( p - T a ) ignition diagram. Most boundaries are quite sharp, and some show evidence of hysteresis. Close to the axes, reaction is slow, non-luminous and non-oscillatory (I). Within a first broad promontory (II) reaction is accompanied by steady luminescence. Crossing the boundary is not accompanied by a step change in reaction rate, but there is a change in character from stable node (in I) to stable focus (in II). Auto-oscillatory luminescence occurs in a closed region (III) wholly within the promontory II. The effects of adding hydrogen on all these modes is to increase the reaction rates markedly and to make them non-isothermal; the boundaries between I, II and III are not as greatly affected. However, systems to which more than 0.10% H 2 have been added also display a new mode, of oscillatory ignition. This appears at first in a region (IV) of high temperatures and pressures but as more H 2 is increased its realm expands and it eventually dominates the ignition diagram, invading the region of luminescence and soon obliterating the oscillatory part completely.

scholarly journals Mariner 6: Ultraviolet spectrum of Mars upper atmosphere

1971 ◽  
Vol 40 ◽  
pp. 253-256 ◽  
Author(s):  
C. A. Barth ◽  
W. G. Fastie ◽  
C. W. Hord ◽  
J. B. Pearce ◽  
K. K. Kelly ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Spectral Region ◽  
Atomic Hydrogen ◽  
Atomic Oxygen ◽  
Ultraviolet Spectrum ◽  
Upper Atmosphere

Emission features from ionized carbon dioxide and carbon monoxide were measured in the 1900- to 4300-Å spectral region. The Lyman-α 1216-Å line of atomic hydrogen and the 1304-, 1356-, and 2972-Å lines of atomic oxygen were observed.

scholarly journals Carbon Monoxide Diffusion Through Porous Walls: Evidence Found in Incidents and Experimental Studies

2018 ◽  
Vol 4 ◽  
Author(s):  
Izabella Vermesi ◽  
Francesco Restuccia ◽  
Carlos Walker-Ravena ◽  
Guillermo Rein
Keyword(s):  
Carbon Monoxide ◽  
Experimental Studies ◽  
Porous Walls

The interaction of β-FeSi2 with atomic hydrogen, carbon monoxide and oxygen

1996 ◽  
Vol 352-354 ◽  
pp. 523-528 ◽  
Author(s):  
P. Rygus ◽  
P.-R. Steiner ◽  
H. Froitzheim
Keyword(s):  
Carbon Monoxide ◽  
Atomic Hydrogen

scholarly journals Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide

2014 ◽  
Vol 43 (12) ◽  
pp. 4639-4652 ◽  
Author(s):  
Anthony F. Cozzolino ◽  
Jared S. Silvia ◽  
Nazario Lopez ◽  
Christopher C. Cummins
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Experimental Studies ◽  
Electron Source ◽  
Computational Studies ◽  
Metal Nitride ◽  
Key Aspects

DFT and experimental studies are used to elucidate key aspects in the design of a transition metal complex that mediates the reduction of dinitrogen by carbon monoxide and an electron source through a terminal metal nitride complex.

Sign in / Sign up

Export Citation Format

Share Document