Kinetics of the reaction between methyl radicals and oxygen atoms between 294 and 900 K

1987 ◽  
Vol 91 (16) ◽  
pp. 4375-4379 ◽  
Author(s):  
Irene R. Slagle ◽  
Dariusz. Sarzynski ◽  
David. Gutman
Keyword(s):  
Methyl Radicals ◽  
Kinetics Of ◽  
Oxygen Atoms

Correlation between the dynamics of oxygen atoms and oxidation kinetics of solid solutions based on Bi2Sr2CaCu2O8

2004 ◽  
Vol 46 (3) ◽  
pp. 424-429
Author(s):  
A. V. Knotko ◽  
A. V. Garshev ◽  
M. N. Pulkin ◽  
V. I. Putlyaev ◽  
S. I. Morozov
Keyword(s):  
Solid Solutions ◽  
Oxidation Kinetics ◽  
Kinetics Of ◽  
Oxygen Atoms

ChemInform Abstract: Kinetics of the Reaction Between Oxygen Atoms and Allyl Radicals.

ChemInform ◽  
1990 ◽  
Vol 21 (33) ◽  
Author(s):  
I. R. SLAGLE ◽  
J. R. BERNHARDT ◽  
D. GUTMAN ◽  
M. A. HANNING-LEE ◽  
M. J. PILLING
Keyword(s):  
Kinetics Of ◽  
Oxygen Atoms

Kinetics of the reaction of methyl radicals with nitrogen dioxide

1981 ◽  
Vol 83 (2) ◽  
pp. 409-412 ◽  
Author(s):  
Fumiaki Yamada ◽  
Irene R. Slagle ◽  
D. Gutman
Keyword(s):  
Nitrogen Dioxide ◽  
Methyl Radicals ◽  
Kinetics Of

Reactions of free radicals with aromatic compounds in the gaseous phase. I. Kinetics of the reaction of methyl radicals with toluene

1964 ◽  
Vol 17 (12) ◽  
pp. 1329 ◽  
Author(s):  
MFR Mulcahy ◽  
DJ Williams ◽  
JR Wilmshurst
Keyword(s):  
Flow System ◽  
Methyl Radicals ◽  
Methyl Radical ◽  
Hydrogen Atoms ◽  
Methyl Group ◽  
Benzyl Radical ◽  
Toluene Molecule ◽  
Benzyl Radicals ◽  
Butyl Peroxide ◽  
Kinetics Of

The kinetics of abstraction of hydrogen atoms from the methyl group of the toluene molecule by methyl radicals at 430-540�K have been determined. The methyl radicals were produced by pyrolysis of di-t-butyl peroxide in a stirred-flow system. The kinetics ,agree substantially with those obtained by previous authors using photolytic methods for generating the methyl radicals. At toluene and methyl-radical concentrations of about 5 x 10-7 and 10-11 mole cm-3 respectively the benzyl radicals resulting from the abstraction disappear almost entirely by combination with methyl radicals at the methylenic position. In this respect the benzyl radical behaves differently from the iso-electronic phenoxy radical, which previous work has shown to combine with a methyl radical mainly at ring positions. The investigation illustrates the application of stirred-flow technique to the study of the kinetics of free-radical reactions.

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