Kinetics, mechanism and thermodynamics of the reversible reaction of methylglyoxal (CH3COCHO) with sulfur(IV)

1987 ◽  
Vol 91 (11) ◽  
pp. 3011-3020 ◽  
Author(s):  
Eric A. Betterton ◽  
Michael R. Hoffmann
Keyword(s):  
Reversible Reaction

scholarly journals Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

2015 ◽  
Vol 44 (11) ◽  
pp. 5041-5044 ◽  
Author(s):  
Susana Luaces ◽  
Ramón Macías ◽  
María José Artigas ◽  
Fernando J. Lahoz ◽  
Luis A. Oro
Keyword(s):  
Reversible Reaction ◽  
Synthesis And Characterization ◽  
Reaction Cycles

New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by the hydrogenation of the alkene ligand.

Mapping the kinetic events in a linear two-step irreversible-reversible reaction mechanism

2017 ◽  
Vol 158 ◽  
pp. 370-380 ◽  
Author(s):  
Daniel Branco P. ◽  
Gregory S. Yablonsky ◽  
Guy B. Marin ◽  
Denis Constales
Keyword(s):  
Reaction Mechanism ◽  
Reversible Reaction

Dynamic combinatorial chemistry with diselenides and disulfides in water

2014 ◽  
Vol 50 (28) ◽  
pp. 3716-3718 ◽  
Author(s):  
Brian Rasmussen ◽  
Anne Sørensen ◽  
Henrik Gotfredsen ◽  
Michael Pittelkow
Keyword(s):  
Combinatorial Chemistry ◽  
Reversible Reaction ◽  
Dynamic Combinatorial Chemistry

Diselenide exchange is introduced as a reversible reaction in dynamic combinatorial chemistry in water at physiological pH.

ChemInform Abstract: SYNTHESIS AND STUDY OF IMIDAZOLE-BEARING COPPER(I) COMPLEXES AND THEIR REVERSIBLE REACTION WITH DIOXYGEN

1985 ◽  
Vol 16 (4) ◽  
Author(s):  
C. L. MERRILL ◽  
L. J. WILSON ◽  
T. J. THAMANN ◽  
T. M. LOEHR ◽  
N. S. FERRIS ◽  
...  
Keyword(s):  
Reversible Reaction

scholarly journals STUDY OF PURUSH SIDDHANT WITH SCIENTIFIC APPROACH

2021 ◽  
Vol 9 (11) ◽  
pp. 2840-2843
Author(s):  
Pramod Kumar ◽  
Pramod Kumar Prasad ◽  
Gupta S.S
Keyword(s):  
Indian Philosophy ◽  
Modern Science ◽  
Reversible Reaction ◽  
Ultimate Truth ◽  
Living World ◽  
Life And Death ◽  
Scientific Approach ◽  
The Mind ◽  
The Universe

The word “Purush" in its most social sense means man but in the aspect of Ayurveda, the term purush is repre- sented as atma or chetana dhatu (chetana-life and dhatu-element). The concept of the existence of atman (soul) is generally not accepted by modern science. According to Indian philosophy, the ultimate truth or absolute soul is one and he is Chetana (Sarvam Khalu Idam Brahm). Treatment of Panchmahabhut Sharir with presence of purush is known as Chikitsya Purush. Purush is supreme soul, pure conscious, unchanging, immortal neither birth nor death. It is essential for the creation of the universe and the living world. In the presence of purush gains knowledge through the mind. All the actions through karmendriyas, desire, pleasure, pain, life and death are per- formed. The purush (Kshetrajy) is lord of the house (Kshetra). The role of Purush in Srusti is laya & parlay which is the same as catalyst’s work in a reversible reaction. Keywords: Purush, Types, Karma Chikitsa, Chaturvinshatika, Rashi, Punarjanma

Importance of reversible reaction for the synthesis of telechelic polymer by means of polycondensation using an excess of one monomer

2021 ◽  
Author(s):  
Takayoshi Katoh ◽  
Tomoya Suzuki ◽  
Yoshihiro Ohta ◽  
Tsutomu Yokozawa
Keyword(s):  
Exchange Reaction ◽  
Reversible Reaction ◽  
Effective Strategy ◽  
Telechelic Polymers ◽  
Cyclic Polymer ◽  
Ester Exchange ◽  
Ester Exchange Reaction ◽  
Telechelic Polymer

We show that reversible polycondensation through alkoxide-catalyzed ester-ester exchange reaction is an effective strategy for the synthesis of telechelic polymers free from contamination with cyclic polymer in the polycondensation of...

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