Yields of molecular hydrogen in the elementary reactions hydroperoxo (HO2) + HO2 and atomic oxygen (1D2) + water

1985 ◽  
Vol 89 (16) ◽  
pp. 3449-3453 ◽  
Author(s):  
Robert J. Glinski ◽  
John W. Birks
Keyword(s):  
Molecular Hydrogen ◽  
Atomic Oxygen ◽  
Elementary Reactions

The effect of vibrational energy on the reaction of molecular hydrogen with atomic oxygen

1975 ◽  
Vol 31 (2) ◽  
pp. 220-224 ◽  
Author(s):  
John H. Birely ◽  
Jerome V.V. Kasper ◽  
Francis Hai ◽  
Lane A. Darnton
Keyword(s):  
Molecular Hydrogen ◽  
Atomic Oxygen ◽  
Vibrational Energy

Product-state-resolved dynamics of the elementary reaction of atomic oxygen with molecular hydrogen, O(3P) + D2 → OD(X2Π) + D

2013 ◽  
Vol 5 (4) ◽  
pp. 315-319 ◽  
Author(s):  
Sridhar A. Lahankar ◽  
Jianming Zhang ◽  
Kenneth G. McKendrick ◽  
Timothy K. Minton
Keyword(s):  
Molecular Hydrogen ◽  
Atomic Oxygen ◽  
Elementary Reaction ◽  
Product State

scholarly journals Intramolecular water-splitting reaction in single collisions of water ions with surfaces

2017 ◽  
Vol 8 (4) ◽  
pp. 2852-2858 ◽  
Author(s):  
Yunxi Yao ◽  
Konstantinos P. Giapis
Keyword(s):  
Water Splitting ◽  
Molecular Hydrogen ◽  
Atomic Oxygen

Direct water splitting into molecular hydrogen and atomic oxygen is demonstrated through single collisions of water ions with generic surfaces at hyperthermal energies.

Infrared chemiluminescence from carbon monoxide in the reactions of atomic oxygen with acetylene and carbon suboxide

1970 ◽  
Vol 317 (1531) ◽  
pp. 575-586 ◽  
Keyword(s):  
Atomic Hydrogen ◽  
Atomic Oxygen ◽  
Flow Reactor ◽  
Reaction System ◽  
Emission Spectra ◽  
Flow Rates ◽  
Elementary Reactions ◽  
Vibration Rotation ◽  
Low Pressures ◽  
Co Emission

Vibration-rotation transitions of CO(X 1 Ʃ + ) have been observed as infrared chemiluminescence from the reactions of O( 3 P) with C 2 H 2 , C 3 O 2 and HC 3 N. The emission spectra, observed from a spherical flow reactor at low pressures (0.1 to 2 Torr) were characteristic for each reaction system, and in some cases depended on the relative flow rates of the reactants and were affected by the addition of atomic hydrogen. These changes in spectral distribution can yield valuable information about the mechanisms of the elementary reactions involved. Thus in the O + C 2 H 2 reaction, the distribution extending to v ' = 14 which predominates at low fuel flows is associated with the reactions O + C 2 H 2 = CO + CH 2 + 48 kcal/mol (200 kJ/mol), O + CH 2 =CO + 2H + 73 kcal/mol (306 kJ/mol). An additional distribution extending up to v ' = 33 (163 kcal/mol, 680 kJ/mol) is observed at high acetylene flows and in the presence of added hydrogen. This is attributed to the reaction O + CH = CO + H + 176 kcal/mol (736 kJ/mol). Similar emission is also observed from the O + C 3 O 2 reaction when atomic hydrogen is added; in its absence, the dominant CO emission comes from levels v ≼ 8 and is attributed to the reaction O + C 3 O 2 = 3CO+115 kcal/mol (480 kJ/mol).

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