In situ measurement of the infrared spectra of insoluble monolayers at the air-water interface

1985 ◽  
Vol 89 (15) ◽  
pp. 3195-3197 ◽  
Author(s):  
Richard A. Dluhy ◽  
Donald G. Cornell
Keyword(s):  
Infrared Spectra ◽  
In Situ Measurement ◽  
Water Interface ◽  
Air Water Interface

In Situ Measurement of the Displacement of Protein Films from the Air/Water Interface by Surfactant

2001 ◽  
Vol 2 (3) ◽  
pp. 1001-1006 ◽  
Author(s):  
Alan R. Mackie ◽  
A. Patrick Gunning ◽  
Mike J. Ridout ◽  
Peter J. Wilde ◽  
J. Rodriguez Patino
Keyword(s):  
In Situ Measurement ◽  
Water Interface ◽  
Protein Films ◽  
Air Water Interface

In Situ Measurement of the FT-IR Spectra of Phospholipid Monolayers at the Air/Water Interface

1988 ◽  
Vol 42 (1) ◽  
pp. 138-141 ◽  
Author(s):  
Richard A. Dluhy ◽  
Norman A. Wright ◽  
Peter R. Griffiths
Keyword(s):  
Detailed Examination ◽  
In Situ Measurement ◽  
Surface Films ◽  
Water Interface ◽  
Monolayer Films ◽  
Air Water Interface ◽  
Monomolecular Films ◽  
Acyl Chains ◽  
Ft Ir

External reflection Fourier transform infrared spectroscopy has been applied to the in situ measurement of the infrared spectra of insoluble phospholipid monolayer films that were spread at the air/water interface. The spreading conditions for the phospholipids [1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC) and 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC)] were chosen to mimic those of liquid-condensed and liquid-expanded surface films, respectively. It is shown that the infrared reflection spectra can identify vibrations due to the hydrocarbon acyl chains, carbonyl ester, and phosphate groups for these monolayer films on water. Detailed examination of the frequencies and polarization properties of the C-H stretching region shows that the liquid-condensed DSPC acyl chains are in a rigid, mostly all-trans configuration, while the liquid-expanded DMPC acyl chains are highly fluid. The spectra demonstrate that the external reflection FT-IR experiment can differentiate between the physical conformation of monomolecular films when water is used as a reflective substrate.

scholarly journals Spin Crossover in Nickel(II) Tetraphenylporphyrinate via Forced Axial Coordination at the Air/Water Interface

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4155
Author(s):  
Alexander V. Shokurov ◽  
Daria S. Kutsybala ◽  
Andrey P. Kroitor ◽  
Alexander A. Dmitrienko ◽  
Alexander G. Martynov ◽  
...  
Keyword(s):  
Spin State ◽  
Spin Crossover ◽  
High Spin State ◽  
Water Interface ◽  
Metal Centers ◽  
Axial Coordination ◽  
Vis Spectroscopy ◽  
Air Water Interface ◽  
Nickel Cation

Coordination-induced spin crossover (CISCO) in nickel(II) porphyrinates is an intriguing phenomenon that is interesting from both fundamental and practical standpoints. However, in most cases, realization of this effect requires extensive synthetic protocols or extreme concentrations of extra-ligands. Herein we show that CISCO effect can be prompted for the commonly available nickel(II) tetraphenylporphyrinate, NiTPP, upon deposition of this complex at the air/water interface together with a ruthenium(II) phthalocyaninate, CRPcRu(pyz)2, bearing two axial pyrazine ligands. The latter was used as a molecular guiderail to align Ni···Ru···Ni metal centers for pyrazine coordination upon lateral compression of the system, which helps bring the two macrocycles closer together and forces the formation of Ni–pyz bonds. The fact of Ni(II) porphyrinate switching from low- to high-spin state upon acquiring additional ligands can be conveniently observed in situ via reflection-absorption UV-vis spectroscopy. The reversible nature of this interaction allows for dissociation of Ni–pyz bonds, and thus, change of nickel cation spin state, upon expansion of the monolayer.

In situ neutron reflectivity studies of the adsorption of DNA by charged diblock copolymer monolayers at the air–water interface

Soft Matter ◽  
2012 ◽  
Vol 8 (27) ◽  
pp. 7161 ◽  
Author(s):  
Po-Wei Yang ◽  
Tsang-Lang Lin ◽  
I-Ting Liu ◽  
Yuan Hu ◽  
Michael James
Keyword(s):  
Diblock Copolymer ◽  
Neutron Reflectivity ◽  
Water Interface ◽  
Air Water Interface

Inorganic mixed phase templated by a fatty acid monolayer at the air–water interface: the Mn and Mg case

2018 ◽  
Vol 20 (9) ◽  
pp. 6629-6637 ◽  
Author(s):  
Alae El Haitami ◽  
Michel Goldmann ◽  
Philippe Fontaine ◽  
Marie-Claude Fauré ◽  
Sophie Cantin
Keyword(s):  
Grazing Incidence ◽  
Water Interface ◽  
X Ray Diffraction ◽  
Inorganic Layer ◽  
X Ray ◽  
First Order ◽  
First Order Phase Transition ◽  
Air Water Interface ◽  
First Order Phase

A first-order phase transition with a peculiar feature is evidenced by means of in situ grazing incidence X-ray diffraction in the 2D organic phase-mediated nucleation of an inorganic layer.

In situ structure and force characterization of 2D nano-colloids at the air/water interface

Soft Matter ◽  
2019 ◽  
Vol 15 (42) ◽  
pp. 8475-8482
Author(s):  
Giovanni Li-Destri ◽  
Roberta Ruffino ◽  
Nunzio Tuccitto ◽  
Giovanni Marletta
Keyword(s):  
Quantitative Determination ◽  
Experimental Method ◽  
Water Interface ◽  
Liquid Interfaces ◽  
Interaction Forces ◽  
Air Water Interface

We have developed a novel experimental method, which enables quantitative determination of interaction forces between interfacial nanoparticles as a function of the inter-particle distance at liquid interfaces.

Real‐Time Probing of Nanowire Assembly Kinetics at the Air–Water Interface by In Situ Synchrotron X‐Ray Scattering

2018 ◽  
Vol 130 (27) ◽  
pp. 8262-8266 ◽  
Author(s):  
Zhen He ◽  
Hui‐Jun Jiang ◽  
Long‐Long Wu ◽  
Jian‐Wei Liu ◽  
Geng Wang ◽  
...  
Keyword(s):  
Real Time ◽  
Water Interface ◽  
X Ray ◽  
X Ray Scattering ◽  
Air Water Interface ◽  
Assembly Kinetics ◽  
Ray Scattering
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