Deuterium isotope effects in condensed-phase thermochemical decomposition reactions of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

S. A. Shackelford; M. B. Coolidge; B. B. Goshgarian; B. A. Loving; R. N. Rogers; J. L. Janney; M. H. Ebinger

doi:10.1021/j100260a034

Deuterium isotope effects in condensed-phase thermochemical decomposition reactions of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

The Journal of Physical Chemistry ◽

10.1021/j100260a034 ◽

1985 ◽

Vol 89 (14) ◽

pp. 3118-3126 ◽

Cited By ~ 35

Author(s):

S. A. Shackelford ◽

M. B. Coolidge ◽

B. B. Goshgarian ◽

B. A. Loving ◽

R. N. Rogers ◽

...

Keyword(s):

Condensed Phase ◽

Isotope Effects ◽

Decomposition Reactions ◽

Deuterium Isotope Effects ◽

Thermochemical Decomposition

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Thermal decomposition of energetic materials. 2. Deuterium isotope effects and isotopic scrambling in condensed-phase decomposition of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

The Journal of Physical Chemistry ◽

10.1021/j100168a025 ◽

1991 ◽

Vol 95 (15) ◽

pp. 5838-5845 ◽

Cited By ~ 51

Author(s):

Richard Behrens ◽

Suryanarayana Bulusu

Keyword(s):

Thermal Decomposition ◽

Condensed Phase ◽

Energetic Materials ◽

Isotope Effects ◽

Phase Decomposition ◽

Deuterium Isotope Effects

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ChemInform Abstract: Deuterium Isotope Effects on the Rates of Thermal Decomposition of 2,2′ ,4,4′,6,6′-Hexanitrostilbene in the Condensed Phase.

ChemInform ◽

10.1002/chin.199303083 ◽

2010 ◽

Vol 24 (3) ◽

pp. no-no

Author(s):

M. KONY ◽

I. J. DAGLEY ◽

D. J. WHELAN

Keyword(s):

Thermal Decomposition ◽

Condensed Phase ◽

Isotope Effects ◽

Deuterium Isotope Effects

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ChemInform Abstract: DEUTERIUM ISOTOPE EFFECTS IN THE THERMOCHEMICAL DECOMPOSITION OF LIQUID 2,4,6-TRINITROTOLUENE- APPLICATION TO MECHANISTIC STUDIES USING ISOTHERMAL DIFFERENTIAL SCANNING CALORIMETRY ANALYSIS

Chemischer Informationsdienst ◽

10.1002/chin.197822107 ◽

1978 ◽

Vol 9 (22) ◽

Author(s):

S. A. SHACKELFORD ◽

J. W. BECKMANN ◽

J. S. WILKES

Keyword(s):

Differential Scanning Calorimetry ◽

Isotope Effects ◽

Differential Scanning Calorimetry Analysis ◽

Mechanistic Studies ◽

Scanning Calorimetry ◽

Deuterium Isotope Effects ◽

Thermochemical Decomposition

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Deuterium isotope effects in the thermochemical decomposition of liquid 2,4,6-trinitrotoluene: application to mechanistic studies using isothermal differential scanning calorimetry analysis

The Journal of Organic Chemistry ◽

10.1021/jo00862a006 ◽

1977 ◽

Vol 42 (26) ◽

pp. 4201-4206 ◽

Cited By ~ 48

Author(s):

S. A. Shackelford ◽

J. W. Beckmann ◽

J. S. Wilkes

Keyword(s):

Differential Scanning Calorimetry ◽

Isotope Effects ◽

Differential Scanning Calorimetry Analysis ◽

Mechanistic Studies ◽

Scanning Calorimetry ◽

Deuterium Isotope Effects ◽

Thermochemical Decomposition

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Deuterium isotope effects on the rates of thermal decomposition of 2,2',4,4',6,6'-hexanitrostilbene in the condensed phase

The Journal of Physical Chemistry ◽

10.1021/j100199a034 ◽

1992 ◽

Vol 96 (20) ◽

pp. 8001-8006 ◽

Cited By ~ 10

Author(s):

Michael Kony ◽

Ian J. Dagley ◽

Daniel J. Whelan

Keyword(s):

Thermal Decomposition ◽

Condensed Phase ◽

Isotope Effects ◽

Deuterium Isotope Effects

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Thermal decomposition of energetic materials. 4. Deuterium isotope effects and isotopic scrambling (H/D, 13C/18O, 14N/15N) in condensed-phase decomposition of 1,3,5-trinitrohexahydro-s-triazine (RDX)

The Journal of Physical Chemistry ◽

10.1021/j100201a037 ◽

1992 ◽

Vol 96 (22) ◽

pp. 8891-8897 ◽

Cited By ~ 47

Author(s):

Richard Behrens ◽

Suryanarayana Bulusu

Keyword(s):

Thermal Decomposition ◽

Condensed Phase ◽

Energetic Materials ◽

Isotope Effects ◽

Phase Decomposition ◽

Deuterium Isotope Effects

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Mechanism of hydration and isomerisation of 4-ethylidene-2,6-di-tert-butyl-2,5-cyclohexadien-1-one. Kinetics, acid-base catalysis and solvent deuterium isotope effects

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19790110 ◽

1979 ◽

Vol 44 (1) ◽

pp. 110-122 ◽

Cited By ~ 2

Author(s):

Jiří Velek ◽

Bohumír Koutek ◽

Milan Souček

Keyword(s):

Aqueous Medium ◽

Rate Equation ◽

Kinetic Data ◽

Isotope Effects ◽

Base Catalysis ◽

Quinone Methide ◽

Reaction Products ◽

Acid Base ◽

Deuterium Isotope Effects ◽

Hydroxybenzyl Alcohol

Competitive hydration and isomerisation of the quinone methide I at 25 °C in an aqueous medium in the region of pH 2.4-13.0 was studied spectrophotometrically. The only reaction products in the studied range of pH are 4-hydroxybenzyl alcohol (II) and 4-hydroxystyrene (III). The form of the overall rate equation corresponds to a general acid-base catalysis. The mechanism of both reactions for three markedly separated pH regions is discussed on the basis of kinetic data and solvent deuterium effect.

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