Intramolecular donor-acceptor systems. 7. Solvent dielectric relaxation effects on the photophysics of 6-(phenylamino)-N,N-dimethyl-2-naphthalenesulfonamides

1983 ◽  
Vol 87 (14) ◽  
pp. 2479-2484 ◽  
Author(s):  
E. M. Kosower ◽  
H. Kanety ◽  
H. Dodiuk ◽  
G. Striker ◽  
T. Jovin ◽  
...  
Keyword(s):  
Dielectric Relaxation ◽  
Relaxation Effects ◽  
Donor Acceptor

On the relationship between matric potential and dielectric properties of organic free soils: a sensitivity study

2009 ◽  
Vol 46 (10) ◽  
pp. 1202-1215 ◽  
Author(s):  
Norman Wagner ◽  
Alexander Scheuermann
Keyword(s):  
Dielectric Relaxation ◽  
Low Frequency ◽  
Bound Water ◽  
Frequency Dispersion ◽  
Strong Relationship ◽  
Sensitivity Study ◽  
Relative Dielectric Permittivity ◽  
Relaxation Processes ◽  
Matric Potential ◽  
Relaxation Effects

High-frequency electromagnetic determination of moisture in porous media, (e.g., soil) is based on the strong relationship between volumetric water content and relative dielectric permittivity. In particular, in fine-grained soils the movement of water is influenced by different surface-bonding forces due to interface processes. The interface effects lead to a number of dielectric relaxation processes (free- and bound-water phase, Maxwell–Wagner effect, counterion relaxation effects). These relaxation processes are the reason for the strong frequency dependence of the electromagnetic material properties below 1 GHz. The matric potential is a measure of the bonding forces on water in the soil. Based on a thermodynamic relationship between soil matric potential and dielectric relaxation behaviour of water in different binding states, a broadband dielectric relaxation model was developed that considers low-frequency dispersion up to 1 MHz as well as losses due to direct-current conductivity. The sensitivity of the model on soil suction was systematically analyzed based on a pedotransfer function (PTF) for soil textures ranging from pure sand up to pure clay. The results are compared with known empirical and semiempirical calibration functions, as well as theoretical mixing models.

Absence of dielectric relaxation effects on intramolecular electron transfer in porphyrin-quinone cyclophanes

1992 ◽  
Vol 198 (6) ◽  
pp. 645-652 ◽  
Author(s):  
F. Pöllinger ◽  
H. Heitele ◽  
M.E. Michel-Beyerle ◽  
C. Anders ◽  
M. Futscher ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Dielectric Relaxation ◽  
Intramolecular Electron Transfer ◽  
Relaxation Effects

Evidence of a donor-acceptor type transition in CuGaSe2

1980 ◽  
Vol 41 (7) ◽  
pp. 707-712 ◽  
Author(s):  
A. Poure ◽  
G. Aguero ◽  
G. Masse ◽  
J.P. Aicardi
Keyword(s):  
Type Transition ◽  
Donor Acceptor
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