Liquid crystals in a fused salt: .beta.,.gamma.-distearoylphosphatidylcholine in N-ethylammonium nitrate

1983 ◽  
Vol 87 (4) ◽  
pp. 533-535 ◽  
Author(s):  
D. F. Evans ◽  
E. W. Kaler ◽  
W. J. Benton
1982 ◽  
Vol 88 (1) ◽  
pp. 89-96 ◽  
Author(s):  
D.Fennell Evans ◽  
Akira Yamauchi ◽  
Ronald Roman ◽  
Ethel Z Casassa

1989 ◽  
Vol 30 (14) ◽  
pp. 1785-1788 ◽  
Author(s):  
David A. Jaeger ◽  
Charles E. Tucker

1985 ◽  
Vol 63 (3) ◽  
pp. 565-570 ◽  
Author(s):  
M. Hadded ◽  
M. Biquard ◽  
P. Letellier ◽  
R. Schaal

Partial molar volumes of water and ethylammonium nitrate EAN are determined accurately in all water–EAN mixtures, between pure water and pure fused salt at 298 K. It has been found that the partial molar volume of water decreases linearly with molar fraction of salt, x, in concentrated solution of EAN (C > 2 mol L−1, x > 0.04). The main thermodynamic relations are established to describe the volumetric behaviour of salt, water, and solution. It has been shown that the intrinsic volume of salt can be identified roughly with the molar volume of the pure fused salt and the value of apparent molar volume of water with the actual volume of water in solution.


1985 ◽  
Vol 63 (12) ◽  
pp. 3587-3592 ◽  
Author(s):  
M. Biquard ◽  
P. Letellier ◽  
M. Fromon

The activity and activity coefficient of water in water and ethylammonium nitrate (EAN) mixtures were determined by vapor pressure measurements between pure water and pure fused salt at 298.15 K. For a wide range of mole fractions of salt, (0.3 < X ≤ 1) the behaviour of water can be described very accurately by a "one parameter" empirical equation which involves activity coefficient, γE, mole fraction of EAN, and limiting Gibbs energy of the dilution of water in pure fused salt, [Formula: see text]:[Formula: see text]Interpretation of experimental results was also attempted by use of the B.E.T. equation. It appears that the energy, ΔEd = E − EL, in those solutions is very low. Partial molar volumes of water and salt are also discussed in relation to empirical and B.E.T. equations. It can be shown that the two equations lead to similar results.


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