Gas-phase NMR investigation of internal rotation in N,N-dimethyltrifluoroacetamide. Phase dependence of kinetic parameters

1983 ◽  
Vol 87 (1) ◽  
pp. 89-94 ◽  
Author(s):  
Brian D. Ross ◽  
Nancy S. True ◽  
Debra L. Decker
Keyword(s):  
Kinetic Parameters ◽  
Gas Phase ◽  
Internal Rotation ◽  
Phase Dependence

Gas-Phase Dynamic NMR Study of the Internal Rotation inN-Trifluoroacetylpyrrolidine

2003 ◽  
Vol 107 (17) ◽  
pp. 3024-3029 ◽  
Author(s):  
Cristina Suarez ◽  
Elisabeth J. Nicholas ◽  
Molly R. Bowman
Keyword(s):  
Gas Phase ◽  
Internal Rotation ◽  
Dynamic Nmr ◽  
Phase Dynamic ◽  
Nmr Study

scholarly journals The kinetics of the hydrogen chloride oxidation

2013 ◽  
Vol 78 (12) ◽  
pp. 2115-2130 ◽  
Author(s):  
Martinez Gonzalez ◽  
Tanja Vidakovic-Koch ◽  
Rafael Kuwertz ◽  
Ulrich Kunz ◽  
Thomas Turek ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Gas Phase ◽  
Hydrogen Chloride ◽  
Reaction Order ◽  
Membrane Electrode ◽  
Polarization Data ◽  
Rate Determining Step ◽  
Electrode Assemblies ◽  
Apparent Kinetic Parameters ◽  
Kinetics Of

Hydrogen chloride (HCl) oxidation has been investigated on technical membrane electrode assemblies in a cyclone flow cell. Influence of Nafion loading, temperature and hydrogen chloride mole fraction in the gas phase has been studied. The apparent kinetic parameters like reaction order with respect to HCl, Tafel slope and activation energy have been determined from polarization data. The apparent kinetic parameters suggest that the recombination of adsorbed Cl intermediate is the rate determining step.

scholarly journals Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – reactions of organic species

2005 ◽  
Vol 5 (4) ◽  
pp. 6295-7168 ◽  
Author(s):  
R. Atkinson ◽  
D. L. Baulch ◽  
R. A. Cox ◽  
J. N. Crowley ◽  
R. F. Hampson ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Gas Phase ◽  
Atmospheric Chemistry ◽  
Kinetic Data ◽  
Photochemical Reactions ◽  
Data Evaluation ◽  
Organic Species ◽  
Summary Sheet

Abstract. This article, the second in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of Organic species, which were last published in 1999, and were updated on the IUPAC website in late 2002. The article consists of a summary sheet, containing the recommended kinetic parameters for the evaluated reactions, and eight appendices containing the data sheets, which provide information upon which the recommendations are made.

Mechanisms and Kinetic Parameters for the Gas-Phase Reactions of 3-Methyl-3-buten-2-one and 3-Methyl-3-penten-2-one with Ozone

2019 ◽  
Vol 123 (13) ◽  
pp. 2745-2755 ◽  
Author(s):  
Xueyu Wang ◽  
Jianfei Sun ◽  
Lei Bao ◽  
Qiong Mei ◽  
Bo Wei ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Gas Phase ◽  
Gas Phase Reactions
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