Photoinduced electron transfer from anions. Part 2. Formation and decay of radical anions of aromatic compounds produced by photoinduced electron transfer from the triphenylstannyl anion

1982 ◽  
Vol 86 (15) ◽  
pp. 2950-2953 ◽  
Author(s):  
Tamotsu Aruga ◽  
Osamu Ito ◽  
Minoru Matsuda
Keyword(s):  
Electron Transfer ◽  
Aromatic Compounds ◽  
Photoinduced Electron Transfer ◽  
Radical Anions

Regio- and stereoselective functionalization of electron-deficient alkenes by organosilicon compounds via photoinduced electron transfer

2003 ◽  
Vol 75 (8) ◽  
pp. 1049-1054 ◽  
Author(s):  
K. Mizuno ◽  
T. Hayamizu ◽  
Hajime Maeda
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Cations ◽  
Reactive Intermediates ◽  
Radical Anions ◽  
Organosilicon Compounds ◽  
Allylic Silanes ◽  
Carbon Radicals

Regio- and stereoselective photoallylation of electron-deficient alkenes by use of allylic silanes via photoinduced electron transfer has been described. Similar photoinduced  functionalization reactions such as arylmethylation, alkylation, and silylation can be achieved by using a variety of organosilicon compounds. These photoreactions proceed via radical cations of organosilicon compounds and radical anions of electron-deficient alkenes as reactive intermediates. The key step of the photoreactions is the attack of carbon radicals, which are generated from the radical cations of organosilicon compounds, on the radical anions of alkenes. The mechanism of the regio- and stereoselective photofunctionalization is discussed.

Surprising differences in the reactivity of cyano aromatic radical anions generated by photoinduced electron transfer

1991 ◽  
Vol 113 (1) ◽  
pp. 358-359 ◽  
Author(s):  
Matthew A. Kellett ◽  
David G. Whitten ◽  
Ian R. Gould ◽  
William R. Bergmark
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Anions ◽  
Aromatic Radical

Determination of rate constants for electron transfer from radical anions of aromatic compounds to diaryl disulfides

1981 ◽  
Vol 103 (18) ◽  
pp. 5484-5489 ◽  
Author(s):  
Hideyuki Tagaya ◽  
Tamotsu Aruga ◽  
Osamu Ito ◽  
Minoru Matsuda
Keyword(s):  
Electron Transfer ◽  
Rate Constants ◽  
Aromatic Compounds ◽  
Radical Anions
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