Vapor adsorption on mica and silicon: entropy effects, layering, and surface forces

1992 ◽  
Vol 96 (8) ◽  
pp. 3395-3403 ◽  
Author(s):  
D. Beaglehole ◽  
H. K. Christenson
Langmuir ◽  
1995 ◽  
Vol 11 (5) ◽  
pp. 1701-1710 ◽  
Author(s):  
Luc J. M. Schlangen ◽  
Luuk K. Koopal ◽  
Martien A. Cohen Stuart ◽  
Johannes Lyklema ◽  
Michel Robin ◽  
...  

Author(s):  
H. Gross ◽  
H. Moor

Fracturing under ultrahigh vacuum (UHV, p ≤ 10-9 Torr) produces membrane fracture faces devoid of contamination. Such clean surfaces are a prerequisite foe studies of interactions between condensing molecules is possible and surface forces are unequally distributed, the condensate will accumulate at places with high binding forces; crystallites will arise which may be useful a probes for surface sites with specific physico-chemical properties. Specific “decoration” with crystallites can be achieved nby exposing membrane fracture faces to water vopour. A device was developed which enables the production of pure water vapour and the controlled variation of its partial pressure in an UHV freeze-fracture apparatus (Fig.1a). Under vaccum (≤ 10-3 Torr), small container filled with copper-sulfate-pentahydrate is heated with a heating coil, with the temperature controlled by means of a thermocouple. The water of hydration thereby released enters a storage vessel.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3811
Author(s):  
Zhongbao Liu ◽  
Jiayang Gao ◽  
Xin Qi ◽  
Zhi Zhao ◽  
Han Sun

In this study, the hydrothermal method was used to synthesize MIL-101(Cr), and activated carbon (AC) with different content was incorporated in to MIL-101(Cr), thereby obtaining AC-MIL-101(Cr) composite material with a huge specific surface area. The physical properties of MIL-101(Cr) and AC-MIL-101(Cr) were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), nitrogen adsorption and desorption and specific surface area testing, and ethanol vapor adsorption performance testing. The results show that with the increase of activated carbon content, the thermal stability of AC-MIL-101(Cr) is improved. Compared with the pure sample, the BET specific surface area and pore volume of AC-MIL-101(Cr) have increased; In the relative pressure range of 0–0.4, the saturated adsorption capacity of AC-MIL-101(Cr) to ethanol vapor decreases slightly. It is lower than MIL-101(Cr), but its adsorption rate is improved. Therefore, AC-MIL-101(Cr)/ethanol vapor has a good application prospect in adsorption refrigeration systems. The exploration of AC-MIL-101(Cr) composite materials in this paper provides a reference for the future application of carbon-based/MOFS composite adsorbent/ethanol vapor working fluid in adsorption refrigeration.


2014 ◽  
Vol 85 (1) ◽  
pp. 013702 ◽  
Author(s):  
Gutian Zhao ◽  
Qiyan Tan ◽  
Li Xiang ◽  
Di Zhang ◽  
Zhonghua Ni ◽  
...  

Author(s):  
Aasif A. Dabbawala ◽  
K. Suresh kumar Reddy ◽  
Hemant Mittal ◽  
Yasser Al Wahedi ◽  
Balasubramanian V. Vaithilingam ◽  
...  

1946 ◽  
Vol 36 (4) ◽  
pp. 410-410
Author(s):  
C. P. Yaglou
Keyword(s):  

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