Zero-field splitting of the first excited triplet state of dibenzocycloheptadienylidene: a carbene to biradical transformation upon electronic excitation

1992 ◽  
Vol 96 (6) ◽  
pp. 2486-2490 ◽  
Author(s):  
A. Despres ◽  
V. Lejeune ◽  
E. Migirdicyan ◽  
M. S. Platz
Keyword(s):  
Triplet State ◽  
Electronic Excitation ◽  
Excited Triplet State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Excited Triplet

scholarly journals Transanular Interaction in [2.2]Phanes: [2.2](2,7)Pyrenophane

1976 ◽  
Vol 31 (10) ◽  
pp. 1189-1192 ◽  
Author(s):  
D. Schweitzer ◽  
K. H. Hausser ◽  
R. G. H. Kirrstetter ◽  
H. A. Staab
Keyword(s):  
Triplet State ◽  
Single Crystals ◽  
Solid Solutions ◽  
Emission Spectra ◽  
Excited Triplet State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Excited Triplet

Abstract The emission spectra of [2.2] (2,7) pyrenophane and the zero field splitting parameters D und E of its excited triplet state were measured in glasses and in small single crystals at 1.3 K. The results are being compared with monomer pyrene and 2,7-dimethylpyrene in liquid and solid solutions as well as in single crystals.

Triplet‐State Zero‐Field‐Splitting Correlations in Substituted Molecules

1967 ◽  
Vol 46 (10) ◽  
pp. 3976-3983 ◽  
Author(s):  
B. Smaller ◽  
E. C. Avery ◽  
J. R. Remko
Keyword(s):  
Triplet State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting
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