High Rydberg states of carbon monoxide (n .gtoreq. 8) as studied by triple-resonant multiphoton ionization

1991 ◽  
Vol 95 (11) ◽  
pp. 4182-4186 ◽  
Author(s):  
Nobuki Hosoi ◽  
Takayuki Ebata ◽  
Mitsuo Ito
1995 ◽  
Vol 15 (2-4) ◽  
pp. 157-165 ◽  
Author(s):  
Kazuhide Tsuji ◽  
Kazuhiko Shibuya ◽  
Kinichi Obi

The resonance enhanced multiphoton ionization method has been applied to the study of NO-Ar van der Waals complex in the nsσ (n = 3,4) Rydberg states. We have assigned the intermolecular vibrations appearing in the ×X˜ excitation spectrum of the complex. The bending structure appeared only with the excitation of the stretching mode in the à state, which was interpreted by intermolecular forces. The E˜-à excitation spectra were independent of the initial intermolecular level in the à state and the dissociation threshold to NO(E2∑+ ) + Ar was determined to be 60950 cm-1. The s–d mixing in the 4sσ orbital would make the intermolecular vibrational structure in the E˜—Ãspectra complex.


1995 ◽  
Vol 102 (4) ◽  
pp. 1515-1527 ◽  
Author(s):  
S. A. Boggis ◽  
J. M. Dyke ◽  
A. N. Hughes ◽  
T. Keszthelyi ◽  
R. Richter ◽  
...  

1993 ◽  
Vol 98 (6) ◽  
pp. 4355-4371 ◽  
Author(s):  
Craig A. Taatjes ◽  
Johanna W. G. Mastenbroek ◽  
Ger van den Hoek ◽  
Jaap G. Snijders ◽  
Steven Stolte

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