Effect of coordinated ligands on interporphyrin photoinduced-electron-transfer rates

1993 ◽  
Vol 97 (51) ◽  
pp. 13637-13642 ◽  
Author(s):  
Devens Gust ◽  
Thomas A. Moore ◽  
Ana L. Moore ◽  
Ho Kwan Kang ◽  
Janice M. DeGraziano ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Rates

Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads

2003 ◽  
Vol 368 (1-2) ◽  
pp. 230-235 ◽  
Author(s):  
Nobuhiro Ohta ◽  
Satoshi Mikami ◽  
Yuji Iwaki ◽  
Minoru Tsushima ◽  
Hiroshi Imahori ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electric Field ◽  
Photoinduced Electron Transfer ◽  
Transfer Rates ◽  
Acceleration And Deceleration

Corrole–ferrocene and corrole–anthraquinone dyads: synthesis, spectroscopy and photochemistry

2015 ◽  
Vol 17 (40) ◽  
pp. 26607-26620 ◽  
Author(s):  
Jaipal Kandhadi ◽  
Venkatesh Yeduru ◽  
Prakriti R. Bangal ◽  
Lingamallu Giribabu
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Charge Separation ◽  
Photoinduced Electron Transfer ◽  
Charge Recombination ◽  
Transfer Rates ◽  
Donor Acceptor

Two different donor–acceptor systems based on corrole–ferrocene (Cor–Fc) and corrole–anthraquinone (Cor–AQ) have been designed and synthesized. Excited state properties of these dyads indicates intramolecular photoinduced electron transfer (PET) take place in these dyads and the electron-transfer rates (kET) was found to be ∼1011s−1. The charge separation (CS) and charge recombination (CR) are found to be identical.

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