Species-associated spectra and upper and lower bounds on the rate constants of reversible intramolecular two-state excited-state processes with added quencher. Global compartmental analysis of the fluorescence decay surface

1993 ◽  
Vol 97 (45) ◽  
pp. 11738-11753 ◽  
Author(s):  
Luc Van Dommelen ◽  
Noel Boens ◽  
Marcel Ameloot ◽  
Frans C. De Schryver ◽  
Andrzej Kowalczyk
Keyword(s):  
Excited State ◽  
Lower Bounds ◽  
Rate Constants ◽  
Compartmental Analysis ◽  
Fluorescence Decay ◽  
Upper And Lower Bounds

Calculated R.R.K.M. unimolecular dissociation rate constants for hydrazine

1969 ◽  
Vol 47 (14) ◽  
pp. 2593-2599 ◽  
Author(s):  
D. W. Setser ◽  
W. C. Richardson
Keyword(s):  
Experimental Data ◽  
Lower Bounds ◽  
Rate Constants ◽  
Chemical Activation ◽  
Dissociation Rate ◽  
Upper And Lower Bounds ◽  
Unimolecular Dissociation ◽  
Complex Models ◽  
Dissociation Rate Constants ◽  
Activated Complex

Unimolecular rate constants for hydrazine dissociation by thermal and chemical activation have been calculated according to the R.R.K.M. theory. The two activated complex models used in the calculations represent plausible upper and lower bounds to the rate constants. The calculations are mainly directed toward establishing expected decomposition to stablilization ratios of N2H4 produced by combination of NH2 radicals; however, a general comparison to available experimental data for hydrazine dissociation is made.

Compartmental analysis of the fluorescence decay surface of intramolecular two-state excited-state processes with added quencher

1992 ◽  
Author(s):  
Noel Boens ◽  
Marcel Ameloot ◽  
Ronn Andriessen ◽  
Luc Van Dommelen ◽  
Frans C. De Schryver ◽  
...  
Keyword(s):  
Excited State ◽  
Compartmental Analysis ◽  
Fluorescence Decay

Intramolecular Excited-State Processes of a Halato-Telechelic Polymer, Evaluated by Global Compartmental Analysis of the Fluorescence Decay Surface with the Use of Model Compounds

1997 ◽  
Vol 30 (19) ◽  
pp. 5582-5590 ◽  
Author(s):  
Jan van Stam ◽  
Frans C. De Schryver ◽  
Noël Boens ◽  
Bart Hermans ◽  
Robert Jérôme ◽  
...  
Keyword(s):  
Excited State ◽  
Compartmental Analysis ◽  
Fluorescence Decay ◽  
Model Compounds ◽  
Telechelic Polymer

scholarly journals Altering the distribution of excited-state lifetimes in aminated GFP chromophores by Ag nanohole arrays

2021 ◽  
Vol 2015 (1) ◽  
pp. 012018
Author(s):  
VR Aslopovsky ◽  
AM Shakhov ◽  
AA Astafiev ◽  
VE Bochenkov
Keyword(s):  
Excited State ◽  
Rate Constants ◽  
Fluorescence Decay ◽  
Lifetime Distribution ◽  
Excited State Lifetime ◽  
Decay Kinetics ◽  
Silver Films ◽  
Nanohole Arrays ◽  
Fluorescence Decay Kinetics ◽  
Gfp Chromophore

Abstract Fluorescence of the modified GFP chromophore diethyl-ABDI-BF2 dispersed in PMMA matrix is studied on top of glass, continuous and perforated optically thin silver films. In polymer, the fluorescence decay kinetics becomes non-exponential and can be described by the distribution of rate constants. The results demonstrate shortening of the excited state lifetime in the presence of silver and broadening of the lifetime distribution caused by the nanoholes.

[14] Compartmental analysis of fluorescence decay surfaces of excited-state processes

1992 ◽  
pp. 314-340 ◽  
Author(s):  
Marcel Mameloot ◽  
Noël Boens ◽  
Ronn Andriessen ◽  
Viviane Van Den Bergh ◽  
Frans C. De Schryver
Keyword(s):  
Excited State ◽  
Compartmental Analysis ◽  
Fluorescence Decay

Kinetics and identifiability of intramolecular two-state excited-state processes: global compartmental analysis of the fluorescence decay surface

1992 ◽  
Vol 96 (15) ◽  
pp. 6331-6342 ◽  
Author(s):  
Noel Boens ◽  
Ronn Andriessen ◽  
Marcel Ameloot ◽  
Luc Van Dommelen ◽  
Frans C. De Schryver
Keyword(s):  
Excited State ◽  
Compartmental Analysis ◽  
Fluorescence Decay
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