Anisotropic nuclear spin interactions in dipotassium tetracyanomercurate(II): a multinuclear solid-state NMR study

1993 ◽  
Vol 97 (30) ◽  
pp. 7863-7869 ◽  
Author(s):  
Gang Wu ◽  
Roderick E. Wasylishen
Keyword(s):  
Solid State ◽  
Nuclear Spin ◽  
Solid State Nmr ◽  
Nmr Study ◽  
Spin Interactions

scholarly journals Anisotropic nuclear spin interactions in H 2 O@C 60 determined by solid-state NMR

2013 ◽  
Vol 371 (1998) ◽  
pp. 20120102 ◽  
Author(s):  
M. Concistrè ◽  
S. Mamone ◽  
M. Denning ◽  
G. Pileio ◽  
X. Lei ◽  
...  
Keyword(s):  
Solid State ◽  
Nuclear Spin ◽  
Solid State Nmr ◽  
Room Temperature ◽  
Chemical Shift Anisotropy ◽  
Water Molecules ◽  
Dipole Interactions ◽  
Nmr Study ◽  
Spin Interactions ◽  
Principal Axes

We report a solid-state NMR study of the anisotropic nuclear spin interactions in H 2 O@C 60 at room temperature. We find evidence of significant dipole–dipole interactions between the water protons, and also a proton chemical shift anisotropy (CSA) interaction. The principal axes of these interaction tensors are found to be perpendicular. The magnitude of the CSA is too large to be explained by a model in which the water molecules are partially aligned with respect to an external axis. The evidence indicates that the observed CSA is caused by a distortion of the geometry or electronic structure of the fullerene cages, in response to the presence of the endohedral water.

The adsorption of chromocene and ferrocene on silica: A solid-state NMR study

2013 ◽  
Vol 744 ◽  
pp. 119-124 ◽  
Author(s):  
Kyle J. Cluff ◽  
Michael Schnellbach ◽  
Casie R. Hilliard ◽  
Janet Blümel
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Study

Investigating Sorption on Iron−Oxyhydroxide Soil Minerals by Solid-State NMR Spectroscopy:  A6Li MAS NMR Study of Adsorption and Absorption on Goethite

2005 ◽  
Vol 109 (39) ◽  
pp. 18310-18315 ◽  
Author(s):  
Ulla Gro Nielsen ◽  
Younkee Paik ◽  
Keinia Julmis ◽  
Martin A. A. Schoonen ◽  
Richard J. Reeder ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Mas Nmr ◽  
Iron Oxyhydroxide ◽  
Soil Minerals ◽  
Solid State Nmr Spectroscopy ◽  
Nmr Study
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