Transfer of methylene from ketene to nitric oxide by photoexcitation of reactant pairs in solid argon below the CH2:C:O dissociation limit

1993 ◽  
Vol 97 (20) ◽  
pp. 5204-5207 ◽  
Author(s):  
Matthew McCluskey ◽  
Heinz Frei
Keyword(s):  
Nitric Oxide ◽  
Dissociation Limit ◽  
Solid Argon ◽  
Reactant Pairs

Energy disequilibrium in the flash photolysis of NO 2

1973 ◽  
Vol 334 (1599) ◽  
pp. 553-568 ◽  
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis ◽  
Vibrational Energy ◽  
Dissociation Limit ◽  
Primary Process ◽  
Transfer Energy ◽  
Vibrationally Excited ◽  
Absolute Concentrations ◽  
The Absolute ◽  
Excited Oxygen

From measurements of the absolute concentrations of vibrationally excited oxygen produced in levels v" = 4 to v" = 13, it is concluded that ca . 20 % of the exothermicity of the reaction O( 3 P) + NO 2 → NO + O + 2 ( v" ≤11) (1) appears initially as vibrational energy in oxygen. Vibrationally excited nitric oxide ( v" = 1, 2) is also observed and may be produced in this reaction or in the primary process NO 2 + hv → NO ( v" ≤ 2) + O( 3 P). More highly excited oxygen ( v" ≤ 15), with energy exceeding the exothermicity of the reaction, is produced in reaction (1) when the NO 2 is first excited by radiation above the dissociation limit near 400 nm. The excited NO 2 thus produced can also transfer energy to nitric oxide. NO 2 * + NO( v" = 0) → NO 2 + NO( v" = 1).

Infrared Spectra of Phenyl Nitrite and Phenoxyl Radical−Nitric Oxide Complex in Solid Argon

2005 ◽  
Vol 109 (19) ◽  
pp. 4261-4266 ◽  
Author(s):  
Rongjing Yang ◽  
Xi Jin ◽  
Wenning Wang ◽  
Kangnian Fan ◽  
Mingfei Zhou
Keyword(s):  
Nitric Oxide ◽  
Infrared Spectra ◽  
Phenoxyl Radical ◽  
Solid Argon
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