Avoided surface crossings and nonadiabatic effects in the electronic quenching reaction lithium(2P) + hydrogen chloride .fwdarw. lithium chloride + hydrogen atom(2S)

1993 ◽  
Vol 97 (19) ◽  
pp. 4989-4995 ◽  
Author(s):  
M. Riad Manaa ◽  
David R. Yarkony
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Chloride ◽  
Lithium Chloride ◽  
Nonadiabatic Effects ◽  
Surface Crossings

LITHIUM CHLORIDE CATALYZED DECARBOXYLATION OF OXALACETIC ACID IN ETHANOL

1964 ◽  
Vol 42 (12) ◽  
pp. 2806-2810 ◽  
Author(s):  
G. W. Kosicki ◽  
S. N. Lipovac ◽  
R. G. Annett
Keyword(s):  
Hydrogen Chloride ◽  
Lithium Chloride ◽  
Pyruvic Acid ◽  
Metal Salt ◽  
Enol Form ◽  
Absorption Peak ◽  
Oxalacetic Acid ◽  
Monovalent Metal

The monovalent metal salt lithium chloride promotes the decarboxylation of oxalacetic acid in ethanol. The absorption peak which appears at 230 mμ during the reaction is interpreted to be the enol form of pyruvic acid. Hydrogen chloride has a similar effect on the decarboxylation.

Product polarization in the calcium(1D2) + hydrogen chloride .fwdarw. calcium monochloride(B) + hydrogen atom reaction

1993 ◽  
Vol 97 (22) ◽  
pp. 5836-5838 ◽  
Author(s):  
M. Garay ◽  
M. Menendez ◽  
E. Verdasco ◽  
J. Castano ◽  
A. Gonzalez Urena
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Chloride
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