Rate constants for the reactions of hydroxyl radicals and chlorine atoms with halogenated aldehydes

1993 ◽  
Vol 97 (18) ◽  
pp. 4683-4688 ◽  
Author(s):  
D. J. Scollard ◽  
J. J. Treacy ◽  
H. W. Sidebottom ◽  
C. Balestra-Garcia ◽  
G. Laverdet ◽  
...  
Keyword(s):  
Hydroxyl Radicals ◽  
Rate Constants ◽  
Chlorine Atoms

ChemInform Abstract: Rate Constants for the Reactions of Hydroxyl Radicals and Chlorine Atoms with Halogenated Aldehydes.

ChemInform ◽  
2010 ◽  
Vol 24 (35) ◽  
pp. no-no
Author(s):  
D. J. SCOLLARD ◽  
J. J. TREACY ◽  
H. W. SIDEBOTTOM ◽  
C. BALESTRA-GARCIA ◽  
G. LAVERDET ◽  
...  
Keyword(s):  
Hydroxyl Radicals ◽  
Rate Constants ◽  
Chlorine Atoms

THE Co60 γ-RADIOLYSIS OF AQUEOUS CYSTINE SOLUTIONS: I. THE EFFECT OF CHLORIDE ION ON THE AMMONIA YIELD

1963 ◽  
Vol 41 (8) ◽  
pp. 1882-1887 ◽  
Author(s):  
W. A. Armstrong ◽  
D. W. Grant
Keyword(s):  
Amino Acid ◽  
Sodium Chloride ◽  
Hydroxyl Radicals ◽  
Rate Constants ◽  
Chloride Ion ◽  
Chlorine Atoms

Sodium chloride has been found to increase the ammonia yield from Co60γ-irradiated cystine in 0.02 M H2SO4. The effect is attributed to the participation of chlorine atoms, which deaminate the amino acid to a greater extent than hydroxyl radicals. The ratio of the rate constants [Formula: see text] is determined to be 24 in 0.02 M H2SO4.

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