HPLC Studies on the Organic Subset of the Oscillatory BZ Reaction 1. Products of the Ce4+-Malonic Acid Reaction

1994 ◽  
Vol 98 (34) ◽  
pp. 8377-8380 ◽  
Author(s):  
Ying Gao ◽  
Horst-Dieter Foersterling ◽  
Zoltan Noszticzius ◽  
Bernhard Meyer
2012 ◽  
Vol 14 (18) ◽  
pp. 6577 ◽  
Author(s):  
Daniel Feldman ◽  
Raphael Nagao ◽  
Tamás Bánsági Jr. ◽  
Irving R. Epstein ◽  
Milos Dolnik

1998 ◽  
Vol 102 (6) ◽  
pp. 922-927 ◽  
Author(s):  
Julia Oslonovitch ◽  
Horst-Dieter Försterling ◽  
Mária Wittmann ◽  
Zoltán Noszticzius

1987 ◽  
Vol 42 (9) ◽  
pp. 963-969 ◽  
Author(s):  
H.D. Försterling ◽  
R. Pachl ◽  
H. Schreiber

The kinetics of the Ce4+-decay and the formation of CO2 are measured in sulfuric acid solutions of malonic acid. The reaction rate is slowed down by Ce3+ -ions due to a reaction of Ce3+ with malonic acid radicals. The primary source of CO2 is the decarboxylation of malonic acid radicals. Implications on the mechanism of the BZ reaction are discussed.


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