Hydrogen Bond Interaction between Self-Assembled Monolayers and Adsorbed Water Molecules and Its Implications for Cluster Formation

1995 ◽  
Vol 99 (39) ◽  
pp. 14198-14200 ◽  
Author(s):  
I. Engquist ◽  
M. Lestelius ◽  
B. Liedberg
Keyword(s):  
Hydrogen Bond ◽  
Cluster Formation ◽  
Adsorbed Water ◽  
Self Assembled Monolayers ◽  
Water Molecules ◽  
Hydrogen Bond Interaction ◽  
Bond Interaction ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Fluorination as a route towards unlocking the hydrogen bond donor ability of phenolic compounds in self-assembled monolayers

CrystEngComm ◽  
2020 ◽  
Vol 22 (14) ◽  
pp. 2425-2428
Author(s):  
Harry Pinfold ◽  
Graham Pattison ◽  
Giovanni Costantini
Keyword(s):  
Hydrogen Bond ◽  
Phenolic Compounds ◽  
Building Block ◽  
Self Assembled Monolayers ◽  
Hydrogen Bond Donor ◽  
Assembled Monolayers ◽  
Donor Ability ◽  
Self Assembled ◽  
Effective Hydrogen

Fluorination turns a prototypical diphenol into an effective hydrogen-bond-donating building block for the formation of 2D phenol–pyridine cocrystals.

scholarly journals Molecular-scale structures of the surface and hydration shell of bioinert mixed-charged self-assembled monolayers investigated by frequency modulation atomic force microscopy

RSC Advances ◽  
2018 ◽  
Vol 8 (43) ◽  
pp. 24660-24664
Author(s):  
Yuki Araki ◽  
Taito Sekine ◽  
Ryongsok Chang ◽  
Tomohiro Hayashi ◽  
Hiroshi Onishi
Keyword(s):  
Hydration Shell ◽  
Self Assembled Monolayers ◽  
Water Molecules ◽  
Self Assembled Monolayer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Molecular Scale ◽  
Assembled Monolayers ◽  
Scale Structures ◽  
Self Assembled

Water molecules above a bioinert mixed-charged self-assembled monolayer (MC-SAM) surface are highly structured compared to those of bioactive SAM surfaces.

Synthesis and Characterization of Titania and Vanadia Thin Films at Organic Self-Assembled Monolayers

1999 ◽  
Vol 576 ◽  
Author(s):  
T. P. Niesen ◽  
J. Wolff ◽  
J. Bill ◽  
M. R. De Guire ◽  
F. Aldinger
Keyword(s):  
Thin Films ◽  
Vanadium Oxide ◽  
Self Assembled Monolayers ◽  
Synthesis And Characterization ◽  
Water Molecules ◽  
Assembled Monolayers ◽  
Titania Films ◽  
Self Assembled ◽  
Deposited Films

ABSTRACTFunctionalized self-assembled monolayers (SAMs) on single-crystal Si wafers have been used as substrates for the deposition of titania and vanadia thin films. The formation of a titanium chelate was used to stabilize an otherwise spontaneously precipitating aqueous titanium solution. Uniform titania films have been synthesized from Ti(O2)2+ in aqueous HCl solutions at 80°C on sulfonated SAMs. Vanadium oxide hydrate films, V2O5·0.7 H2O, have been directly formed from aqueous vanadate solutions on NH2-terminated SAMs at 45°C. In the as-deposited films, water molecules were intercalated between the vanadium oxide layers. Subsequent annealing at 350°C in air led to nanocrystalline V2O5.

Analysis of structures with saturated hydrogen bonding

2007 ◽  
Vol 63 (1) ◽  
pp. 132-141 ◽  
Author(s):  
James H. Loehlin ◽  
Elizabeth L. N. Okasako
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Self Assembled Monolayers ◽  
Donor And Acceptor ◽  
Assembled Monolayers ◽  
Graph Set ◽  
Hydrogen Bond Patterns ◽  
Self Assembled ◽  
Acceptor Numbers

All simple structures with saturated hydrogen bonding (SHB) are classified into eight categories on the basis of the donor and acceptor numbers on the atoms at each end of the hydrogen bonds. Examples from the literature are included where known, along with seven structures investigated as part of this study (five have SHB). Graph-set descriptions of the hydrogen-bond patterns are given for each of these structures and for some selected literature examples. The structures presented are: piperazine (I), morpholinium chloride (II) and iodide (III) [(II) and (III) are not SHB], three 1:1 cocrystals of diols with 1,4-phenylenediamine (PDA) – PDA·1,8-octane diol (IV), PDA·1,10-decane diol (V), and PDA·1,12-dodecane diol (VI) and 6-amino-1-hexanol (VII). This study discusses some structures that show limitations of the graph-set model, along with possible suggestions to cover these limitations. The cocrystalline PDA·aliphatic diol structures may provide details applicable to the structure of self-assembled monolayers of aliphatic thiol molecules on Au(111) surfaces.

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