Photoacoustic Calorimetry at High Pressure: A New Approach to Determination of Bond Strengths. Estimation of the M-L Bond Dissociation Energy of M(CO)5L (M = Cr, Mo; L = H2, N2) in n-Heptane Solution

1995 ◽  
Vol 99 (31) ◽  
pp. 12016-12020 ◽  
Author(s):  
Eoin F. Walsh ◽  
Vladimir K. Popov ◽  
Michael W. George ◽  
Martyn Poliakoff
Keyword(s):  
High Pressure ◽  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
New Approach ◽  
Photoacoustic Calorimetry ◽  
Bond Dissociation ◽  
Bond Strengths

Determination of Rh–C Bond Dissociation Energy in Methyl(porphyrinato)rhodium(III) Complexes: a New Application of Photoacoustic Calorimetry

2001 ◽  
Vol 30 (4) ◽  
pp. 284-285 ◽  
Author(s):  
Gang Li ◽  
Fei Fei Zhang ◽  
Na Pi ◽  
Hui Lan Chen ◽  
Shu Yi Zhang ◽  
...  
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Photoacoustic Calorimetry ◽  
Bond Dissociation

Determination of the heat of formation of trimethylindium and calculation of the mean In—CH3 bond dissociation energy

1968 ◽  
Vol 46 (10) ◽  
pp. 1633-1634 ◽  
Author(s):  
W. D. Clark ◽  
S. J. W. Price
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Chloroform Solution ◽  
Kinetic Studies ◽  
Heat Of Formation ◽  
Enthalpy Of Reaction ◽  
Kcal Mole ◽  
Bond Dissociation ◽  
The Mean

The enthalpy of reaction of In(CH3)3,c with a chloroform solution of bromine is −162.5 kcal mole−1. With this value ΔHf0298[In(CH3)3,c] = 29.5 kcal mole−1 and ΔHf0298[In(CH3)3,g] = 41.1 kcal mole−1. Combining the latter with ΔHf0298[CH3,g] = 33.2 kcal mole−1 and ΔHf0298[In,g] = 58.2 kcal mole−1 then gives E(In—CH3) = 38.9 kcal mole−1. From previous kinetic studies D[(CH3)2In—CH3] + D[In—CH3] = 87.9 kcal mole−1. Hence D[CH3In—CH3] = 28.8 kcal mole−1.

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