Efficient Recovery of Carbon Dioxide from Flue Gases of Coal-Fired Power Plants by Cyclic Fixed-Bed Operations over K2CO3-on-Carbon

1998 ◽  
Vol 37 (1) ◽  
pp. 185-191 ◽  
Author(s):  
Hiromu Hayashi ◽  
Jun Taniuchi ◽  
Nobuyoshi Furuyashiki ◽  
Shigeru Sugiyama ◽  
Shinichi Hirano ◽  
...  
2019 ◽  
Vol 23 (6) ◽  
pp. 4-7
Author(s):  
A.M. Pogodaev ◽  
A.F. Shimansky ◽  
Yu.I. Storozhev ◽  
Ya.V. Kazantsev ◽  
V.S. Zlobin

The thermodynamics of the process of calcium sulfate decomposition is considered. An adsorbent for cleaning flue gases from sulfur dioxide in the form of sludge from alumina production is proposed. Conducted semi-industrial experiments on cleaning the flue gases of small thermal power plants and boiler houses from sulfur dioxide using a laboratory installation. Established high (more than 90%) the effectiveness of the proposed adsorbent. The unique possibility of flue gas cleaning from nitrogen oxides of thermal devices using lignite fuel is revealed. A scheme of sequential flue gas cleaning in a suspended and fixed bed of the adsorbent is proposed.


Radiocarbon ◽  
2007 ◽  
Vol 49 (2) ◽  
pp. 325-330 ◽  
Author(s):  
K M Hämäläinen ◽  
H Jungner ◽  
O Antson ◽  
J Räsänen ◽  
K Tormonen ◽  
...  

A preliminary investigation of the biocarbon fraction in carbon dioxide emissions of power plants using both fossil- and biobased fuels is presented. Calculation of the biocarbon fraction is based on radiocarbon content measured in power plant flue gases. Samples were collected directly from the chimneys into plastic sampling bags. The 14C content in CO2 was measured by accelerator mass spectrometry (AMS). Flue gases from power plants that use natural gas, coal, wood chips, bark, plywood residue, sludge from the pulp factory, peat, and recovered fuel were measured. Among the selected plants, there was one that used only fossil fuel and one that used only biofuel; the other investigated plants burned mixtures of fuels. The results show that 14C measurement provides the possibility to determine the ratio of bio and fossil fuel burned in power plants.


2020 ◽  
Vol 178 ◽  
pp. 01062
Author(s):  
Sergey A. Glazyrin ◽  
Mikhail G. Zhumagulov ◽  
Zhanar A. Aydimbaeva ◽  
Abay M. Dostiyarov

For 30 years research has been carried out on the use of wastewater from thermal power plants and industrial boilers, as well as on the use and extraction of various components from flue gases such as carbon dioxide, sulfur and nitrogen. Technological solutions were developed and implemented in various productions at various times: use of acid-forming components of flue gases for the regeneration of cation exchangers; carbon dioxide from flue gases of 99.9% purity with “food” quality; technical nitrogen of 95-99 purity from flue gases; wastewater usage to increase the degree of sulfur oxides from flue gases. The article presents a technological solution for the integrated utilization of flue gases and wastewater from a thermal power plant with high-pressure boilers burning solid fuels.


2021 ◽  
pp. 229-229
Author(s):  
Sergey Glazyrin ◽  
Zhanar Aidymbayeva ◽  
Abay Dostiyarov ◽  
Mikhail Zhumagulov ◽  
Nikolay Zlatov ◽  
...  

The results of laboratory studies carried out to identify the possibility and effectiveness of technologies for the complex recycling of components of flue gases and wastewater from thermal power plants and industrial boilers are presented. The following factors were investigated: the degree of saturation of water solutions with carbon dioxide, the efficiency of using these solutions for the regeneration of cation exchangers, the properties of regeneration solutions intended for the regeneration of cation exchange filters prepared using components of flue gases obtained from the combustion of organic fuel in the laboratory by saturating water of various compositions, the degree of saturation of condensate and waste water with components of flue gases, as well as the degree of regeneration of cation exchangers with such regeneration solutions. After research in the laboratory, a laboratory installation was created in an industrial environment to determine the properties of solutions obtained from wastewater and flue gases obtained after production processes at a power plant. The technologies were developed for the complex recycling of flue gases and waste water from thermal power plants with the production of carbon dioxide with a purity of 99.9%, technical nitrogen with a purity of 95%, special solutions for the regeneration of cation exchangers in water purification plants of industrial enterprises. The results obtained make it possible to minimize the volume of emissions into the atmosphere and the volume of waste water from thermal power plants


Author(s):  
Hong Lu ◽  
Luke Schideman ◽  
Qing Ye ◽  
Yongqi Lu

Cobalt–manganese composite catalysts in a reverse-flow fixed-bed reactor showed excellent activity and selectivity for reduction of residual O2 for CO2 purification from pressurized oxy-combustion flue gases.


Clay Minerals ◽  
2015 ◽  
Vol 50 (1) ◽  
pp. 31-40 ◽  
Author(s):  
Magdalena Wdowin ◽  
Mariusz Macherzyński ◽  
Rafał Panek ◽  
Jerzy Górecki ◽  
Wojciech Franus

AbstractThe removal of gaseous mercury from flue gases from coal-fired power plants is currently an environmental challenge under investigation. Therefore, the main aim of this paper was to evaluate the suitability of faujasite group zeolites (Na-X) to adsorb mercury compounds. Previous, initial tests showed negligible Hg0 uptake by Na-X zeolite, but silver impregnation improved adsorption markedly. Therefore, the testing of mercury adsorption from flue gases into Ag+- impregnated Na-X synthetic zeolite (Ag-X zeolite) derived from coal fly ash was carried out. This material was characterized by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy, X-ray fluorescence and nitrogen adsorption/desorption before being evaluated for mercury removal from exhaust gas. After preliminary mercury adsorption tests (fixed bed) under a nitrogen atmosphere, the adsorbent was examined with a simulated flue gas composition under various conditions, i.e. weight of zeolite, temperature of experiment and zeolite in powder and granulated forms. The removal of mercury was shown to depend on the sorbent texture (powder or granulate), exhaust gas flow rate and contact time, as well as the temperature of the experiment. The Ag-X zeolite tested reduced the level of mercury in the flue gas and, depending on the experimental conditions, long-time mercury breakthrough ranges from 15 to 40% were obtained. The best results for mercury capture were obtained for granulated material.


2019 ◽  
Vol 2 (3) ◽  
pp. 141-151
Author(s):  
O. E. Gnezdova ◽  
E. S. Chugunkova

Introduction: greenhouses need microclimate control systems to grow agricultural crops. The method of carbon dioxide injection, which is currently used by agricultural companies, causes particular problems. Co-generation power plants may boost the greenhouse efficiency, as they are capable of producing electric energy, heat and cold, as well as carbon dioxide designated for greenhouse plants.Methods: the co-authors provide their estimates of the future gas/electricity rates growth in the short term; they have made a breakdown of the costs of greenhouse products, and they have also compiled the diagrams describing electricity consumption in case of traditional and non-traditional patterns of power supply; they also provide a power distribution pattern typical for greenhouse businesses, as well as the structure and the principle of operation of a co-generation unit used by a greenhouse facility.Results and discussion: the co-authors highlight the strengths of co-generation units used by greenhouse facilities. They have also identified the biological features of carbon dioxide generation and consumption, and they have listed the consequences of using carbon dioxide to enrich vegetable crops.Conclusion: the co-authors have formulated the expediency of using co-generation power plants as part of power generation facilities that serve greenhouses.


1991 ◽  
Vol 24 (7) ◽  
pp. 277-284 ◽  
Author(s):  
E. Gomólka ◽  
B. Gomólka

Whenever possible, neutralization of alkaline wastewater should involve low-cost acid. It is conventional to make use of carbonic acid produced via the reaction of carbon dioxide (contained in flue gases) with water according to the following equation: Carbon dioxide content in the flue gas stream varies from 10% to 15%. The flue gas stream may either be passed to the wastewater contained in the recarbonizers, or. enter the scrubbers (which are continually sprayed with wastewater) from the bottom in oountercurrent. The reactors, in which recarbonation occurs, have the ability to expand the contact surface between gaseous and liquid phase. This can be achieved by gas phase dispersion in the liquid phase (bubbling), by liquid phase dispersion in the gas phase (spraying), or by bubbling and spraying, and mixing. These concurrent operations are carried out during motion of the disk aerator (which is a patent claim). The authors describe the functioning of the disk aerator, the composition of the wastewater produced during wet gasification of carbide, the chemistry of recarbonation and decarbonation, and the concept of applying the disk aerator so as to make the wastewater fit for reuse (after suitable neutralization) as feeding water in acetylene generators.


Author(s):  
Michael O’Sullivan ◽  
Michael Gravatt ◽  
Joris Popineau ◽  
John O’Sullivan ◽  
Warren Mannington ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3860
Author(s):  
Mária Hagarová ◽  
Milan Vaško ◽  
Miroslav Pástor ◽  
Gabriela Baranová ◽  
Miloš Matvija

Corrosion of boiler tubes remains an operational and economic limitation in municipal waste power plants. The understanding of the nature, mechanism, and related factors can help reduce the degradation process caused by corrosion. The chlorine content in the fuel has a significant effect on the production of gaseous components (e.g., HCl) and condensed phases on the chloride base. This study aimed to analyze the effects of flue gases on the outer surface and saturated steam on the inner surface of the evaporator tube. The influence of gaseous chlorides and sulfates or their deposits on the course and intensity of corrosion was observed. The salt melts reacted with the steel surface facing the flue gas flow and increased the thickness of the oxide layer up to a maximum of 30 mm. On the surface not facing the flue gas flow, they disrupted the corrosive layer, reduced its adhesion, and exposed the metal surface. Beneath the massive deposits, a local overheating of the inner surface of the evaporator tubes occurred, which resulted in the release of the protective magnetite layer from the surface. Ash deposits reduce the boiler’s thermal efficiency because they act as a thermal resistor for heat transfer between the flue gases and the working medium in the pipes. The effect of insufficient feedwater treatment was evinced in the presence of mineral salts in the corrosion layer on the inner surface of the tube.


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