Mechanism and Temperature-Dependent Kinetics of the Dehydration oftert-Butyl Alcohol in Hot Compressed Liquid Water

1997 ◽  
Vol 36 (1) ◽  
pp. 23-41 ◽  
Author(s):  
Xiaodong Xu ◽  
Michael Jerry Antal ◽  
Donald G. M. Anderson
Keyword(s):  
Liquid Water ◽  
Butyl Alcohol ◽  
Temperature Dependent ◽  
Compressed Liquid ◽  
Kinetics Of

Mechanism and Kinetics of the Acid-Catalyzed Dehydration of 1- and 2-Propanol in Hot Compressed Liquid Water

1998 ◽  
Vol 37 (10) ◽  
pp. 3820-3829 ◽  
Author(s):  
Michael Jerry Antal, ◽  
Magnus Carlsson ◽  
Xiaodong Xu ◽  
Donald G. M. Anderson
Keyword(s):  
Liquid Water ◽  
Compressed Liquid ◽  
Mechanism And Kinetics ◽  
Acid Catalyzed ◽  
Kinetics Of

Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Transfer Functions ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Oxidation Of Co ◽  
Kinetics Of Oxidation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Kinetics Of

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.

Temperature Dependent Kinetics of the OH/HO2/O3Chain Reaction by Time-Resolved IR Laser Absorption Spectroscopy

2000 ◽  
Vol 104 (17) ◽  
pp. 3964-3973 ◽  
Author(s):  
Sergey A. Nizkorodov ◽  
Warren W. Harper ◽  
Bradley W. Blackmon ◽  
David J. Nesbitt
Keyword(s):  
Absorption Spectroscopy ◽  
Laser Absorption Spectroscopy ◽  
Temperature Dependent ◽  
Time Resolved ◽  
Laser Absorption ◽  
Ir Laser ◽  
Kinetics Of

scholarly journals Kinetics of gluten protein-insolubilisation during pasta processing: Decoupling between time- and temperature-dependent effects

2019 ◽  
Vol 88 ◽  
pp. 103-109 ◽  
Author(s):  
Coline Martin ◽  
Marie-Hélène Morel ◽  
Adrien Reau ◽  
Bernard Cuq
Keyword(s):  
Gluten Protein ◽  
Temperature Dependent ◽  
Kinetics Of

Computational analysis of the effect of [Tea][Ms] and [Tea][H2PO4] ionic liquids on the structure and stability of Aβ(17–42) amyloid fibrils

2021 ◽  
Vol 23 (11) ◽  
pp. 6695-6709
Author(s):  
D. Gobbo ◽  
A. Cavalli ◽  
P. Ballone ◽  
A. Benedetto
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Liquid Water ◽  
Computational Analysis ◽  
Amyloid Fibrils ◽  
Aβ Peptides ◽  
Structure And Stability ◽  
Water Solutions ◽  
Kinetics Of

Tight coordination of peptides by organic anions driven by hydrogen bonding affects the fibrillation kinetics of Aβ peptides in ionic liquid/water solutions.

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