Phase Equilibria of Mixtures Containing Glycol andn-Alkane: Experimental Study of Infinite Dilution Activity Coefficients and Modeling Using the Cubic-Plus-Association Equation of State

2009 ◽  
Vol 48 (24) ◽  
pp. 11202-11210 ◽  
Author(s):  
Waheed Afzal ◽  
Martin P. Breil ◽  
Pascal Théveneau ◽  
Amir H. Mohammadi ◽  
Georgios M. Kontogeorgis ◽  
...  
Keyword(s):  
Experimental Study ◽  
Equation Of State ◽  
Phase Equilibria ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Infinite Dilution Activity Coefficients

Solid-Fluid Phase Equilibria Measurement for Mixtures of Methane, Carbon-Dioxide and N-Hexadecane

2021 ◽  
Author(s):  
Oluwakemi Victoria Eniolorunda ◽  
Antonin Chapoy ◽  
Rod Burgass
Keyword(s):  
Experimental Data ◽  
Carbon Dioxide ◽  
Equation Of State ◽  
Phase Equilibria ◽  
Activity Coefficients ◽  
Fluid Phase ◽  
Ternary Mixtures ◽  
Binary Interaction ◽  
Thermodynamic Models ◽  
Methane Carbon

Abstract In this study, new experimental data using a reliable approach are reported for solid-fluid phase equilibrium of ternary mixtures of Methane-Carbon-dioxide- n-Hexadecane for 30-73 mol% CO2 and pressures up to 24 MPa. The effect of varying CO2 composition on the overall phase transition of the systems were investigated. Three thermodynamic models were used to predict the liquid phase fugacity, this includes the Peng Robison equation of state (PR-EoS), Soave Redlich-Kwong equation of state (SRK-EoS) and the Cubic plus Association (CPA) equation of state with the classical mixing rule and a group contribution approach for calculating binary interaction parameters in all cases. To describe the wax (solid) phase, three activity coefficient models based on the solid solution theory were investigated: the predictive universal quasichemical activity coefficients (UNIQUAC), Universal quasi-chemical Functional Group activity coefficients (UNIFAC) and the predictive Wilson approach. The solid-fluid equilibria experimental data gathered in this experimental work including those from saturated and under-saturated conditions were used to check the reliability of the various phase equilibria thermodynamic models.

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