Water-Dispersed Conductive Polypyrroles Doped with Lignosulfonate and the Weak Temperature Dependence of Electrical Conductivity

2009 ◽  
Vol 48 (21) ◽  
pp. 9498-9503 ◽  
Author(s):  
Chao Yang ◽  
Peng Liu
Keyword(s):  
Electrical Conductivity ◽  
Temperature Dependence ◽  
Weak Temperature Dependence

Electrical Conductivity of Chloro(phenyl)glyoxime and Its Co(II), Ni(II) and Cu(II) Complexes

2003 ◽  
Vol 68 (7) ◽  
pp. 1233-1242 ◽  
Author(s):  
Orhan Turkoglu ◽  
Mustafa Soylak ◽  
Ibrahim Belenli
Keyword(s):  
Electrical Conductivity ◽  
Temperature Dependence ◽  
Electric Conductivity ◽  
Crystal Structures ◽  
Elemental Analysis ◽  
Analysis Data ◽  
Elemental Analysis Data ◽  
The Stability ◽  
Xrd Patterns ◽  
Metal Ligand

Chloro(phenyl)glyoxime, a vicinal dioxime, and its Ni(II), Cu(II) and Co(II) complexes were prepared. XRD patterns of the complexes point to similar crystal structures. IR and elemental analysis data revealed the 1:2 metal-ligand ratio in the complexes. The Co(II) complex is a dihydrate. Temperature dependence of electrical conductivity of the solid ligand and its complexes was measured in the temperature range 25-250 °C; it ranged between 10-14-10-6 Ω-1 cm-1 and increased with rising temperature. The activation energies were between 0.61-0.80 eV. The Co(II) complex has lower electric conductivity than the Ni(II) and Cu(II) complexes. This difference in the conductivity has been attributed to differences in the stability of the complexes.

Temperature dependence of the transient and AC electrical conductivity of porous silicon thin films

2003 ◽  
Vol 101 (1-3) ◽  
pp. 334-337 ◽  
Author(s):  
M. Theodoropoulou ◽  
C.A. Krontiras ◽  
N. Xanthopoulos ◽  
S.N. Georga ◽  
M.N. Pisanias ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Conductivity ◽  
Porous Silicon ◽  
Temperature Dependence ◽  
Ac Electrical Conductivity ◽  
Silicon Thin Films

scholarly journals Особенности электрических свойств кристаллов ниобата лития, выращенных из распалава с флюсом K-=SUB=-2-=/SUB=-O

2019 ◽  
Vol 61 (7) ◽  
pp. 1270
Author(s):  
А.В. Яценко ◽  
С.В. Евдокимов ◽  
М.Н. Палатников ◽  
Н.В. Сидоров
Keyword(s):  
Electrical Conductivity ◽  
Lithium Niobate ◽  
Temperature Dependence ◽  
Proton Conductivity ◽  
Pyroelectric Coefficient ◽  
Strong Anisotropy ◽  
Temperature Range ◽  
Lithium Niobate Crystals

The temperature dependence of the electrical conductivity and the primary pyroelectric coefficient of lithium niobate crystals LiNbO3 grown from a melt with K2O flux was investigated in the range of 292–450 K . It is shown that these crystals are characterized by a strong anisotropy of electrical conductivity, and in the temperature range studied, proton conductivity dominates.

scholarly journals SYNTHESIS AND ELECTRICAL CONDUCTIVITY OF SOLID SOLUTIONS OF THE SYSTEM RbF-PbF2-SnF2

2019 ◽  
Vol 85 (5) ◽  
pp. 60-68
Author(s):  
Yuliay Pogorenko ◽  
Anatoliy Omel’chuk ◽  
Roman Pshenichny ◽  
Anton Nagornyi
Keyword(s):  
Activation Energy ◽  
Electrical Conductivity ◽  
Temperature Dependence ◽  
Solid Solutions ◽  
Basic Structure ◽  
Elementary Cell ◽  
Initial Structure ◽  
Fluoride Ions ◽  
Temperature Range ◽  
Order Of Magnitude

In the system RbF–PbF2–SnF2 are formed solid solutions of the heterovalent substitution RbxPb0,86‑xSn1,14F4-x (0 < x ≤ 0,2) with structure of β–PbSnF4. At x > 0,2 on the X-ray diffractograms, in addition to the basic structure, additional peaks are recorded that do not correspond to the reflexes of the individual fluorides and can indicate the formation of a mixture of solid solutions of different composition. For single-phase solid solutions, the calculated parameters of the crystal lattice are satisfactorily described by the Vegard rule. The introduction of ions of Rb+ into the initial structure leads to an increase in the parameter a of the elementary cell from 5.967 for x = 0 to 5.970 for x = 0.20. The replacement of a part of leads ions to rubium ions an increase in electrical conductivity compared with β–PbSnF4 and Pb0.86Sn1.14F4. Insignificant substitution (up to 3.0 mol%) of ions Pb2+ at Rb+ at T<500 K per order of magnitude reduces the conductivity of the samples obtained, while the nature of its temperature dependence is similar to the temperature dependence of the conductivity of the sample β-PbSnF4. By replacing 5 mol. % of ions with Pb2+ on Rb+, the fluoride ion conductivity at T> 450 K is higher than the conductivity of the initial sample Pb0,86Sn1,14F4 and at temperatures below 450 K by an order of magnitude smaller. With further increase in the content of RbF the electrical conductivity of the samples increases throughout the temperature range, reaching the maximum values at x≥0.15 (σ573 = 0.34–0.41 S/cm, Ea = 0.16 eV and σ373 = (5.34–8.16)•10-2 S/cm, Ea = 0.48–0.51 eV, respectively). In the general case, the replacement of a part of the ions of Pb2+ with Rb+ to an increase in the electrical conductivity of the samples throughout the temperature range. The activation energy of conductivity with an increase in the content of RbF in the low-temperature region in the general case increases, and at temperatures above 400 K is inversely proportional decreasing. The nature of the dependence of the activation energy on the concentration of the heterovalent substituent and its value indicate that the conductivity of the samples obtained increases with an increase in the vacancies of fluoride ions in the structure of the solid solutions.

scholarly journals DC conductivity of polyethylene and crosslinked polyethylene measured with a dynamic temperature program

2017 ◽  
Author(s):  
Hossein Ghorbani ◽  
Carl-Olof Olsson ◽  
Marc Jeroense
Keyword(s):  
Electrical Conductivity ◽  
Temperature Dependence ◽  
Thermal Conditions ◽  
Dc Conductivity ◽  
Protective Film ◽  
Dynamic Temperature ◽  
Operation Conditions ◽  
Heating And Cooling ◽  
Arrhenius Temperature Dependence ◽  
Arrhenius Temperature

<p>Electrical conductivity of HVDC cable insulation materials is important for its function. It is very practical to evaluate this parameter by DC conductivity measurements on press molded polymeric plates samples. While in real operation conditions, the insulation undergoes both static and dynamic thermal conditions, most of the published research in this area is still focused only on steady state thermal conditions. In this work, the focus is instead on the behavior of electrical conductivity under dynamic thermal conditions. Press molded XLPE and LDPE plate samples with different preparations are tested under 25 kV/mm DC field with a dynamic temperature profile ranging from room temperature to 90 °C.<br />It was discovered that in many cases, the measured conductivity during dynamic measurements strongly deviates from the expected Arrhenius temperature dependence; instead the conductivity shows a nonmonotonic<br />temperature dependence manifested as conductivity peaks during heating and cooling. The behavior is found to be strongly related to the type of protective film used during press molding of the sample; further degassing leads to a reduction of the nonmonotonic temperature dependence and with long<br />degassing the behavior tends to the expected Arrhenius temperature dependence.</p>

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