Chemistry of Styrene Oxide. Comparison with Phenyl Glycidyl Ether in Model Compound Reactions

1957 ◽  
Vol 49 (7) ◽  
pp. 1107-1109 ◽  
Author(s):  
Leon Schechter ◽  
John Wynstra ◽  
Raymond Kurkjy
Keyword(s):  
Model Compound ◽  
Styrene Oxide ◽  
Glycidyl Ether ◽  
Phenyl Glycidyl Ether

scholarly journals Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4044
Author(s):  
Muneer Shaik ◽  
Vamshi K. Chidara ◽  
Srinivas Abbina ◽  
Guodong Du
Keyword(s):  
Maleic Anhydride ◽  
Ring Opening ◽  
Styrene Oxide ◽  
Glycidyl Ether ◽  
Thermal Characterization ◽  
Relative Activity ◽  
Phenyl Glycidyl Ether ◽  
Scanning Calorimetry ◽  
The Difference ◽  
Block Terpolymers

Ring opening copolymerization (ROCOP) of epoxides and cyclic anhydrides has become an attractive approach for the synthesis of biodegradable polyesters with various compositions. Encouraged by the efficiency and versatility of a series of amido-oxazolinate zinc complexes, in this study they were shown to be active catalysts for the synthesis of unsaturated polyesters via ROCOP of maleic anhydride and various epoxides. The relative activity of epoxides in these reactions was observed to be styrene oxide > cyclohexene oxide > phenyl glycidyl ether, which could be correlated with the electronic and steric features of the substrate. To provide more structural possibilities for the polyesters, the difference in epoxide reactivity was exploited in an attempt to prepare block terpolymers from one anhydride and two epoxides. Terpolymerization was carried out in one or two steps in a single pot. The thermal characterization by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques suggested that the resulting materials were mostly random terpolymers.

scholarly journals Copolymerization of Phthalic Anhydride with Epoxides Catalyzed by Amine-bis(phenolate) Chromium(III) Complexes

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1785
Author(s):  
Wiktor Bukowski ◽  
Agnieszka Bukowska ◽  
Aleksandra Sobota ◽  
Maciej Pytel ◽  
Karol Bester
Keyword(s):  
Phthalic Anhydride ◽  
Styrene Oxide ◽  
Glycidyl Ether ◽  
Molar Ratio ◽  
Phenyl Glycidyl Ether ◽  
Cyclohexene Oxide ◽  
Catalytic Systems ◽  
Co Catalyst ◽  
Co Catalysts ◽  
Organic Bases

The effect of ligand structure on the catalytic activity of amine-bis(phenolate) chromium(III) complexes in the ring-opening copolymerization of phthalic anhydride and a series epoxides was studied. Eight complexes differing in the donor-pendant group (R1) and substituents (R2) in phenolate units were examined as catalysts of the model reaction between phthalic anhydride and cyclohexane oxide in toluene. They were used individually or as a part of the binary catalytic systems with nucleophilic co-catalysts. The co-catalyst was selected from the following organic bases: PPh3, DMAP, 1-butylimidazole, or DBU. The binary catalytic systems turned out to be more active than the complexes used individually, and DMAP proved to be the best choice as a co-catalyst. When the molar ratio of [PA]:[epoxide]:[Cr]:[DMAP] = 250:250:1:1 was applied, the most active complex (R1-X = CH2NMe2, R2 = F) allowed to copolymerize phthalic anhydride with differently substituted epoxides (cyclohexene oxide, 4-vinylcyclohexene oxide, styrene oxide, phenyl glycidyl ether, propylene oxide, butylene oxide, and epichlorohydrin) within 240 min at 110 °C. The resulting polyesters were characterized by Mn up to 20.6 kg mol−1 and narrow dispersity, and they did not contain polyether units.

Bioresolution of racemic phenyl glycidyl ether by a putative recombinant epoxide hydrolase from Streptomyces griseus NBRC 13350

2017 ◽  
Vol 33 (5) ◽  
Author(s):  
Priya Saini ◽  
Naveen Kumar ◽  
Shadil Ibrahim Wani ◽  
Shilpi Sharma ◽  
Swapandeep Singh Chimni ◽  
...  
Keyword(s):  
Epoxide Hydrolase ◽  
Glycidyl Ether ◽  
Streptomyces Griseus ◽  
Phenyl Glycidyl Ether

ChemInform Abstract: Reaction of Phenyl Glycidyl Ether with β-Urethanoalcohols.

ChemInform ◽  
2010 ◽  
Vol 25 (11) ◽  
pp. no-no
Author(s):  
V. V. MIKHEEV ◽  
N. G. GAFIATULLIN
Keyword(s):  
Glycidyl Ether ◽  
Phenyl Glycidyl Ether

Kinetics and mechanism of the reaction of phenyl glycidyl ether with aniline

1975 ◽  
Vol 17 (8) ◽  
pp. 1892-1900 ◽  
Author(s):  
Kh.A. Arutyunyan ◽  
A.O. Tonoyan ◽  
S.P. Davtyan ◽  
B.A. Rozenberg ◽  
N.S. Yenikolopyan
Keyword(s):  
Glycidyl Ether ◽  
Kinetics And Mechanism ◽  
Phenyl Glycidyl Ether ◽  
Mechanism Of The Reaction
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