Iron Pentacarbonyl as Antiknock Agent in Alcohol Motor Fuels

1945 ◽  
Vol 37 (6) ◽  
pp. 577-579 ◽  
Author(s):  
Isadore Pitesky ◽  
Richard Wiebe
Keyword(s):  
Iron Pentacarbonyl ◽  
Motor Fuels ◽  
Antiknock Agent

Alkylation of Cymantrene with 1-Bromoadamantane Initiated by Iron Pentacarbonyl

INEOS OPEN ◽  
2019 ◽  
Vol 2 (1) ◽  
Author(s):  
Т. Т. Vasil'eva ◽  
◽  
H. H. Hambardzumyan ◽  
N. Е. Mysova ◽  
O. N. Gorunova ◽  
...  
Keyword(s):  
Iron Pentacarbonyl

DEVELOPMENT OF THE COMBUSTION CHAMBER OF GAS ENGINE, CONVERTED ON THE BASIS OF DIESELS D-120 OR D-144 ENGINES TO WORK FOR ON LIQUEFIED PETROLEUM GAS

2019 ◽  
pp. 2-8
Author(s):  
Serhii Kovalov
Keyword(s):  
Combustion Chamber ◽  
Compression Ratio ◽  
Diesel Engines ◽  
Combustion Engine ◽  
Motor Fuel ◽  
Liquefied Petroleum Gas ◽  
Gas Engine ◽  
Chamber Volume ◽  
Motor Fuels ◽  
Dynamic Cycle

The expediency of using vehicles of liquefied petroleum gas as a motor fuel, as com-pared with traditional liquid motor fuels, in particular with diesel fuel, is shown. The advantages of converting diesel engines into gas ICEs with forced ignition with respect to conversion into gas diesel engines are substantiated. The analysis of methods for reducing the compression ratio in diesel engines when converting them into gas ICEs with forced ignition has been carried out. It is shown that for converting diesel engines into gas ICEs with forced ignition, it is advisable to use the Otto thermo-dynamic cycle with a decrease in the geometric degree of compression. The choice is grounded and an open combustion chamber in the form of an inverted axisymmetric “truncated cone” is developed. The proposed shape of the combustion chamber of a gas internal combustion engine for operation in the LPG reduces the geometric compression ratio of D-120 and D-144 diesel engines with an unseparated spherical combustion chamber, which reduces the geometric compression ratio from ε = 16,5 to ε = 9,4. The developed form of the combustion chamber allows the new diesel pistons or diesel pistons which are in operation to be in operation to be refined, instead of making special new gas pistons and to reduce the geometric compression ratio of diesel engines only by increasing the combustion chamber volume in the piston. This method of reducing the geometric degree of compression using conventional lathes is the most technologically advanced and cheap, as well as the least time consuming. Keywords: self-propelled chassis SSh-2540, wheeled tractors, diesel engines D-120 and D-144, gas engine with forced ignition, liquefied petroleum gas (LPG), compression ratio of the internal com-bustion engine, vehicles operating in the LPG.

Catalysts for hydrogenation of CO2 into components of motor fuels

2020 ◽  
pp. 1-18
Author(s):  
Yu.V. Bilokopytov ◽  
◽  
S.L. Melnykova ◽  
N.Yu. Khimach ◽  
◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysts ◽  
Fossil Fuels ◽  
Catalyst Stability ◽  
Co2 Conversion ◽  
Active Components ◽  
Synthesis Conditions ◽  
Hydrogenation Of Co2 ◽  
Mesoporous Zeolites ◽  
Motor Fuels

CO2 is a harmful greenhouse gas, a product of chemical emissions, the combustion of fossil fuels and car exhausts, and it is a widely available source of carbon. The review considers various ways of hydrogenation of carbon dioxide into components of motor fuels - methanol, dimethyl ether, ethanol, hydrocarbons - in the presence of heterogeneous catalysts. At each route of conversion of CO2 (into oxygenates or hydrocarbons) the first stage is the formation of CO by the reverse water gas shift (rWGS) reaction, which must be taken into account when catalysts of process are choosing. The influence of chemical nature, specific surface area, particle size and interaction between catalyst components, as well as the method of its production on the CO2 conversion processes is analyzed. It is noted that the main active components of CO2 conversion into methanol are copper atoms and ions which interact with the oxide components of the catalyst. There is a positive effect of other metals oxides additives with strong basic centers on the surface on the activity of the traditional copper-zinc-aluminum oxide catalyst for the synthesis of methanol from the synthesis gas. The most active catalysts for the synthesis of DME from CO2 and H2 are bifunctional. These catalysts contain both a methanol synthesis catalyst and a dehydrating component, such as mesoporous zeolites with acid centers of weak and medium strength, evenly distributed on the surface. The synthesis of gasoline hydrocarbons (≥ C5) is carried out through the formation of CO or CH3OH and DME as intermediates on multifunctional catalysts, which also contain zeolites. Hydrogenation of CO2 into ethanol can be considered as an alternative to the synthesis of ethanol through the hydration of ethylene. High activation energy of carbon dioxide, harsh synthesis conditions as well as high selectivity for hydrocarbons, in particular methane remains the main problems. Further increase of selectivity and efficiency of carbon dioxide hydrogenation processes involves the use of nanocatalysts taking into account the mechanism of CO2 conversion reactions, development of methods for removing excess water as a by-product from the reaction zone and increasing catalyst stability over time.

ETERMINATION IRON AND MANGANESE CONTENT IN MOTOR FUELS

2017 ◽  
Vol 59 (2) ◽  
pp. 097-102
Author(s):  
Anastasiya A. Kotlova ◽  
◽  
Ilya A. Belous ◽  
Anastasiya V. Kiyashko ◽  
Roman S. Edigarev ◽  
...  
Keyword(s):  
Manganese Content ◽  
Motor Fuels ◽  
Iron And Manganese
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