Promotive Effect of SO2 on the Activity of a Deactivated Commercial Selective Catalytic Reduction Catalyst: An in situ DRIFT Study

2014 ◽  
Vol 53 (42) ◽  
pp. 16229-16234 ◽  
Author(s):  
Yanke Yu ◽  
Jinxiu Wang ◽  
Jinsheng Chen ◽  
Xiaoran Meng ◽  
Yanting Chen ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Selective Catalytic Reduction Catalyst ◽  
Promotive Effect ◽  
In Situ Drift

In situ DRIFT study on NH3 selective catalytic reduction of NO over HBEA zeolite doped with CeO2

2020 ◽  
Vol 506 ◽  
pp. 144715 ◽  
Author(s):  
Yun Shi ◽  
Xiaoxiang Wang ◽  
Liang Chen ◽  
Sujing Li ◽  
Chao Wu ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Reduction Of No ◽  
In Situ Drift

Activity and SO2 resistance of amorphous CeaTiOx catalysts for the selective catalytic reduction of NO with NH3: in situ DRIFT studies

2016 ◽  
Vol 6 (19) ◽  
pp. 7151-7162 ◽  
Author(s):  
Zhiping Zhang ◽  
Liqiang Chen ◽  
Zhibin Li ◽  
Pengying Li ◽  
Fulong Yuan ◽  
...  
Keyword(s):  
High Activity ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Strong Interactions ◽  
Sulfur Resistance ◽  
Reduction Of No ◽  
Scr Of No ◽  
So2 Resistance ◽  
In Situ Drift

Amorphous Ce0.3TiOx exhibits a high activity and sulfur resistance for NH3-SCR of NO due to the strong interactions between Ce and Ti.

Experimental and kinetic analysis of hydrothermal aging effects on ammonia adsorption capacity over a commercial Cu-zeolite selective catalytic reduction catalyst

2018 ◽  
Vol 233 (12) ◽  
pp. 3030-3042
Author(s):  
Tae Joong Wang ◽  
In Hyuk Im
Keyword(s):  
Adsorption Capacity ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Adsorption Site ◽  
Selective Catalytic Reduction Catalyst ◽  
Aging Effects ◽  
Hydrothermal Aging ◽  
Ammonia Adsorption ◽  
Fresh Catalyst ◽  
Reduction Catalysts

Ammonia/urea selective catalytic reduction is an efficient technology to control NOx emission from diesel engines. One of its critical challenges is the performance degradation of selective catalytic reduction catalysts due to the hydrothermal aging experienced in real-world operations during the lifetime. In this study, hydrothermal aging effects on the reduction of ammonia adsorption capacity over a commercial Cu-zeolite selective catalytic reduction catalyst were investigated under actual engine exhaust conditions. Ammonia adsorption site densities of the selective catalytic reduction catalysts aged at two different temperatures of 750°C and 850°C for 25 h with 10% H2O were experimentally measured and compared to that of fresh catalyst on a dynamometer test bench with a heavy-duty diesel engine. The test results revealed that hydrothermal aging significantly decreased the ammonia adsorption capacity of the current commercial Cu-zeolite selective catalytic reduction catalyst. Hydrothermal treatment at 750°C reduced the ammonia adsorption site to 62.5% level of that of fresh catalyst, while hydrothermal treatment at 850°C lowered the adsorption site to 37.0% level of that of fresh catalyst. Also, in this study, numerical simulation and kinetic analysis were carried out to quantify the impact of hydrothermal aging on the reduction of ammonia adsorption capacity by introducing an aging coefficient. The kinetic parameter calibrations based on actual diesel engine tests with a commercial monolith Cu-zeolite selective catalytic reduction catalyst provided a highly realistic kinetic parameter set of ammonia adsorption/desorption and enabled a mathematical description of hydrothermal aging effect.

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