Determination of the Pitzer Interaction Parameters at 273.15 K from the Freezing-Point Data Available for NaCl and KCl Solutions

2014 ◽  
Vol 53 (13) ◽  
pp. 5608-5616 ◽  
Author(s):  
Mehdi Hasan ◽  
Jaakko I. Partanen ◽  
Kari P. Vahteristo ◽  
Marjatta Louhi-Kultanen
Keyword(s):  
Freezing Point ◽  
Interaction Parameters ◽  
Point Data ◽  
Pitzer Interaction Parameters

scholarly journals The accurate determination of the freezing-points of alloys, and a study of valency effects in certain alloys of silver

1937 ◽  
Vol 160 (901) ◽  
pp. 282-303 ◽  
Keyword(s):  
Freezing Point ◽  
Equilibrium Diagram ◽  
Accurate Determination ◽  
Freezing Points ◽  
Experimental Errors ◽  
Series Of Experiments ◽  
Point Data ◽  
Many Sources ◽  
Straight Lines

In the alloys of silver with the four elements immediately following it in the Periodic Table, the silver rich alloys give rise to primary substitutional solid solutions for which the phase boundaries in the equilibrium diagram show well-defined valency effects. When the diagrams are plotted in atomic percentages, the liquidus and solidus curves fall more steeply with increasing valency of the solute, whilst the extent of the solid solution becomes less. It was shown (Hume-Rothery, Mabbott and Channel-Evans 1934) that, to a first approximation, the liquidus curves followed a simple valency rule, such that alloys of identical equivalent composition had identical freezing-points, and, hence, in dilute solutions where the liquidus curves were straight lines, the atomic depression of freezing-point was proportional to the valency of the solute. The experimental errors of 1 or 2°C. in the freezing-point data prevented an exact proof of a whole number law, and the present paper describes more accurate determinations of the freezing-points of these alloys. The first part of the experimental work was carried out by one of the authors (W. H. -R.) working alone, and the later work by the two authors together. It is convenient to refer to the two series of experiments as the early work and the later work respectively. In order to increase the accuracy of the liquidus determinations it has been necessary to examine many sources of error, and this work is described in 2; 3 contains the experimental results, which are discussed in 4.

Cryoscopy of Milk: Effect of Variations in the Method

1966 ◽  
Vol 49 (3) ◽  
pp. 511-515 ◽  
Author(s):  
R W Henningson
Keyword(s):  
Statistical Analysis ◽  
Sample Size ◽  
Freezing Point ◽  
Collaborative Study ◽  
Sample Temperature ◽  
Milk Samples ◽  
Two Samples ◽  
Temperature Rate

Abstract Bath level, sample temperature, rate of stirring, degree of supercooling, sample size, sample isolation, and refreezing of the sample were the variables in the thermistor cryoscopic method for the determination of the freezing point value of milk chosen for study. Freezing point values were determined for two samples of milk and two secondary salt standards utilizing eight combinations of the seven variables in two test patterns. The freezing point value of the salt standards ranged from –0.413 to –0.433°C and from –0.431 to –0.642°C. The freezing point values of the milk samples ranged from –0.502 to –0.544°C and from –0.518 to –0.550°C. Statistical analysis of the data showed that sample isolation was a poor procedure and that other variables produced changes in the freezing point value ranging from 0.001 to 0.011°C. It is recommended that specific directions be instituted for the thermistor cryoscopic method, 15.040–15.041, and that the method be subjected to a collaborative study.

In situ freezing point determination of cryolite baths utilising resistometer measurements

2014 ◽  
Vol 18 (12) ◽  
pp. 3339-3344 ◽  
Author(s):  
Graeme A. Snook ◽  
Katherine McGregor ◽  
Andrew J. Urban
Keyword(s):  
Freezing Point ◽  
Point Determination
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