Analysis of Adsorbent-Based Warm CO2 Capture Technology for Integrated Gasification Combined Cycle (IGCC) Power Plants

2014 ◽  
Vol 53 (27) ◽  
pp. 11145-11158 ◽  
Author(s):  
Zan Liu ◽  
William H. Green
Author(s):  
Michele Vascellari ◽  
Daniele Cocco ◽  
Giorgio Cau

Two power generation systems with pre-combustion CO2 capture fuelled with hydrogen from coal gasification are analyzed and compared from a thermodynamic and economic standpoint. The first solution, referred as Integrated Gasification Combined Cycle with CO2 Removal (IGCC-CR), is fuelled with hydrogen produced by the integrated gasification section. The second, referred as Integrated Gasification Hydrogen Cycle (IGHC), is based on the oxycombustion of hydrogen, producing steam that expands through an advanced high temperature steam turbine. The two H2 production sections are similar for both power plants, some minor modifications having been made to achieve better integration with the corresponding power sections. System performance is investigated using coherent assumptions to enable comparative analysis on the same basis. The plants have overall efficiencies of around 39.8% for IGCC-CR and 40.6% for IGHC, slightly lower than conventional IGCCs (without CO2 capture) with a CO2 removal efficiencies of 91% and 100% respectively. Lastly a preliminary economic analysis shows an increase in the cost of electricity compared to conventional IGCCs of about 44% for IGCC-CR and 50% IGHC.


Author(s):  
Eric Liese

This paper examines the arrangement of a solid oxide fuel cell (SOFC) within a coal gasification cycle, this combination generally being called an integrated gasification fuel cell cycle. This work relies on a previous study performed by the National Energy Technology Laboratory (NETL) that details thermodynamic simulations of integrated gasification combined cycle (IGCC) systems and considers various gasifier types and includes cases for 90% CO2 capture (2007, “Cost and Performance Baseline for Fossil Energy Plants, Vol. 1: Bituminous Coal and Natural Gas to Electricity,” National Energy Technology Laboratory Report No. DOE/NETL-2007/1281). All systems in this study assume a Conoco Philips gasifier and cold-gas clean up conditions for the coal gasification system (Cases 3 and 4 in the NETL IGCC report). Four system arrangements, cases, are examined. Cases 1 and 2 remove the CO2 after the SOFC anode. Case 3 assumes steam addition, a water-gas-shift (WGS) catalyst, and a Selexol process to remove the CO2 in the gas cleanup section, sending a hydrogen-rich gas to the fuel cell anode. Case 4 assumes Selexol in the cold-gas cleanup section as in Case 3; however, there is no steam addition, and the WGS takes places in the SOFC and after the anode. Results demonstrate significant efficiency advantages compared with IGCC with CO2 capture. The hydrogen-rich case (Case 3) has better net electric efficiency compared with typical postanode CO2 capture cases (Cases 1 and 2), with a simpler arrangement but at a lower SOFC power density, or a lower efficiency at the same power density. Case 4 gives an efficiency similar to Case 3 but also at a lower SOFC power density. Carbon deposition concerns are also discussed.


Author(s):  
Peng Pei ◽  
Manohar Kulkarni

Integrated Gasification Combined Cycle (IGCC) is believed to be one of the most promising technologies to offer electricity and other de-carbon fuels with carbon capture requirement as well as to meet other emission regulations at a relatively low cost. As one of the most important parts, different gasification technologies can greatly influence the performance of the system. This paper develops a model to examine the feasibilities and advantages of using Ultra Superheated Steam (USS) gasification technology in IGCC power plant with carbon dioxide capture and storage (CCS). USS gasification technology converts coal into syngas by the endothermic steam reforming reaction, and the heat required for this reaction is provided by the sensible heat in the ultra superheated steam. A burner utilizes synthetic air (21% O2 and 79% H2O) to burn fuel gas to produce the USS flame for the gasification process. The syngas generated from USS gasification has a higher hydrogen fraction (more than 50%) then other gasification processes. This high ratio of hydrogen is considered to be desired for a “capture-ready” IGCC plant. After gas cleanup and water gas shift reaction, the syngas goes to the Selexol process for carbon dioxide removal. Detailed calculations and analysis are performed to test the performance of USS gasification technology used in IGCC generation systems. Final results such as net output, efficiency penalty for CO2 capture part, and net thermal efficiency are calculated and compared when three different coal types are used. This paper uses published data of USS gasification from previous research at the University of North Dakota. The model also tries to treat the IGCC with carbon dioxide capture system as a whole thermal system, the superheated steam used in USS gasification can be provided by extracting steam from the lower pressure turbine in the Rankine Cycle. The model will make reasonable use of various waste energies and steams for both mechanical and chemical processes to improve the performance of the plant, and incorporate CO2 capture system into the design concept of the power plant.


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