On-Line Optimizing Control of Bulk Free Radical Polymerization Reactors under Temporary Loss of Temperature Regulation:  Experimental Study on a 1-L Batch Reactor

2006 ◽  
Vol 45 (22) ◽  
pp. 7530-7539 ◽  
Author(s):  
Shrikant A. Bhat ◽  
Deoki N. Saraf ◽  
Sanjay Gupta ◽  
Santosh K. Gupta
Keyword(s):  
Experimental Study ◽  
Free Radical ◽  
Radical Polymerization ◽  
Temperature Regulation ◽  
Batch Reactor ◽  
Free Radical Polymerization ◽  
On Line ◽  
Optimizing Control

Aqueous free-radical polymerization of PEGMEMA macromer: kinetic studies via an on-line 1H NMR technique

2012 ◽  
Vol 21 (10) ◽  
pp. 683-688 ◽  
Author(s):  
Vahid Najafi ◽  
Farshid Ziaee ◽  
Kourosh Kabiri ◽  
Mohammad Jalal Zohouriaan Mehr ◽  
Hossein Abdollahi ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
1H Nmr ◽  
Free Radical Polymerization ◽  
Kinetic Studies ◽  
On Line

Online Optimizing Control of Molecular Weight Properties in Batch Free-Radical Polymerization Reactors

2002 ◽  
Vol 41 (24) ◽  
pp. 6120-6131 ◽  
Author(s):  
Costas Kiparissides ◽  
Panagiotis Seferlis ◽  
George Mourikas ◽  
A. Julian Morris
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Optimizing Control

Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates

2021 ◽  
Author(s):  
Mariya Edeleva ◽  
Yoshi W. Marien ◽  
Paul H. M. Van Steenberge ◽  
Dagmar R. D'hooge
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Temperature Regulation ◽  
Butyl Acrylate ◽  
Free Radical Polymerization ◽  
Side Reactions

Conventional batch solution free radical polymerization of n-butyl acrylate with thermal initiators such as AIBN is known to be strongly exothermic and influenced by highly activated side reactions such as backbiting and β-scission.

Effects of initiator loss by chain transfer in free-radical polymerization using batch operations

1992 ◽  
Vol 437 (1901) ◽  
pp. 489-499
Keyword(s):  
Free Radical ◽  
Molecular Mass ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Batch Reactor ◽  
Monomer Concentration ◽  
Free Radical Polymerization ◽  
Monomer Conversion ◽  
Degree Of Polymerization ◽  
Initial Monomer

In the free-radical polymerization of vinyl monomers, initiator can be lost by chain transfer. This loss affects the monomer conversion with time in a batch reactor and can influence the expected molecular mass of the polymer as the reaction proceeds. Expressions are developed which allow these effects to be quantified. Examples indicate when these effects are important. The instantaneous number-average degree of polymerization passes through a minimum as the initiator concentration is increased. The location of this minimum depends on the importance of initiator loss by chain transfer. Initial monomer concentration affects the absolute value of molecular mass but has little influence on the relative effects of initiator loss by chain transfer.

scholarly journals Impact of Fluid Flow on Free Radical Polymerization in a Batch Reactor

10.5772/64156 ◽  
2016 ◽  
Author(s):  
Gerardo M. Pineda-Torres ◽  
Cecilia Durán-Valencia ◽  
Fernando Barragán-Aroche ◽  
Simon López-Ramírez
Keyword(s):  
Fluid Flow ◽  
Free Radical ◽  
Radical Polymerization ◽  
Batch Reactor ◽  
Free Radical Polymerization
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