In Situ Measurement of Dissolved Hydrogen during the Liquid-Phase Hydrogenation of DinitrilesMethod and Case Study

2005 ◽  
Vol 44 (25) ◽  
pp. 9770-9775 ◽  
Author(s):  
Peter Schärringer ◽  
Thomas E. Müller ◽  
Wolfgang Kaltner ◽  
Johannes A. Lercher
1979 ◽  
Vol 44 (9) ◽  
pp. 2624-2632 ◽  
Author(s):  
Zdeněk Kozák ◽  
Martin Čapka

Kinetics of liquid phase hydrogenation of alkenes catalysed by homogeneous Rh(I) complexes prepared in situ from di-μ,μ'-chloro-bis/di(cyclooctene)rhodium/ and 3-(triethoxysilyl)propyldiphenylphosphine and by heterogenised analogues anchored to silica have been studied. The reaction was found to be first order in hydrogen, alkene and catalyst. Compared to the soluble complexes, the supported catalyst turned out to be substantially more stable. At 0.3-0.6%Rh concentrations on the support, the activity of the catalyst was not affected by pore size within 4-10 nm region. The supported catalysts prepared by functionalization of the support followed by formation of the Rh complex were more active then their homogeneous analogues.


2016 ◽  
Vol 55 (23) ◽  
pp. 6607-6618 ◽  
Author(s):  
Muhammad N. Siddiquee ◽  
Arno de Klerk

2012 ◽  
Vol 45 (1) ◽  
pp. 162-168 ◽  
Author(s):  
Masoud Ghandehari ◽  
Cristian S. Vimer ◽  
Ioannis Ioannou ◽  
Alexey Sidelev ◽  
Weihua Jin ◽  
...  

2018 ◽  
pp. 60-67
Author(s):  
Henrika Pihlajaniemi ◽  
Anna Luusua ◽  
Eveliina Juntunen

This paper presents the evaluation of usersХ experiences in three intelligent lighting pilots in Finland. Two of the case studies are related to the use of intelligent lighting in different kinds of traffic areas, having emphasis on aspects of visibility, traffic and movement safety, and sense of security. The last case study presents a more complex view to the experience of intelligent lighting in smart city contexts. The evaluation methods, tailored to each pilot context, include questionnaires, an urban dashboard, in-situ interviews and observations, evaluation probes, and system data analyses. The applicability of the selected and tested methods is discussed reflecting the process and achieved results.


2013 ◽  
Vol 16 (1) ◽  
pp. 59-67

<p>The Soil Science Institute of Thessaloniki produces new digitized Soil Maps that provide a useful electronic database for the spatial representation of the soil variation within a region, based on in situ soil sampling, laboratory analyses, GIS techniques and plant nutrition mathematical models, coupled with the local land cadastre. The novelty of these studies is that local agronomists have immediate access to a wide range of soil information by clicking on a field parcel shown in this digital interface and, therefore, can suggest an appropriate treatment (e.g. liming, manure incorporation, desalination, application of proper type and quantity of fertilizer) depending on the field conditions and cultivated crops. A specific case study is presented in the current work with regards to the construction of the digitized Soil Map of the regional unit of Kastoria. The potential of this map can easily be realized by the fact that the mapping of the physicochemical properties of the soils in this region provided delineation zones for differential fertilization management. An experiment was also conducted using remote sensing techniques for the enhancement of the fertilization advisory software database, which is a component of the digitized map, and the optimization of nitrogen management in agricultural areas.</p>


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