Synthesis of Hydrated Aluminum Phosphate, AlPO4·1.5H2O (AlPO4−H3), by Controlled Reactive Crystallization in Sulfate Media

2005 ◽  
Vol 44 (21) ◽  
pp. 8033-8038 ◽  
Author(s):  
Felipe Lagno ◽  
George P. Demopoulos
Keyword(s):  
Aluminum Phosphate ◽  
Hydrated Aluminum ◽  
Reactive Crystallization

A model for the structure of the hydrated aluminum phosphate, kingite determined by ab initio powder diffraction methods

2003 ◽  
Vol 88 (1) ◽  
pp. 235-239 ◽  
Author(s):  
Kia S. Wallwork ◽  
Allan Pring ◽  
Max R. Taylor ◽  
Brett A. Hunter
Keyword(s):  
Ab Initio ◽  
Powder Diffraction ◽  
Aluminum Phosphate ◽  
Hydrated Aluminum

Diagenetic fluorapatite and aluminum phosphate–sulphate in the Paleoproterozoic Thelon Formation and Hornby Bay Group, northwestern Canadian Shield

2006 ◽  
Vol 43 (5) ◽  
pp. 617-629 ◽  
Author(s):  
Q Gall ◽  
J A Donaldson
Keyword(s):  
Earth Element ◽  
Aluminum Phosphate ◽  
Canadian Shield ◽  
Northwestern Part ◽  
Athabasca Basin ◽  
Thelon Basin ◽  
Hydrated Aluminum ◽  
Element Bearing ◽  
Diagenetic Fluids ◽  
Lines Of Evidence

In the northwestern part of the Canadian Shield, fluorapatite and a rare-earth element-bearing hydrated aluminum phosphate–sulphate mineral (APS) occur as cements in continental successions near the base of the Paleoproterozoic Thelon Formation (Thelon Basin) and Hornby Bay Group (Hornby Bay Basin). These minerals occupy interstitial sites, form euhedral crystals, display micro-scale zonation, make up part of an unmetamorphosed paragenetic assemblage, and are distributed in correlative units across thousands of square kilometres, suggesting a diagenetic origin. Stratigraphy, geochronology, and other lines of evidence suggest that the Thelon Formation and Hornby Bay Group containing these phosphatic cements, as well as the Ellice Formation and Athabasca Group, are correlative and may have been originally interconnected. The evidence suggests that the basal Thelon Formation and the Hornby Bay Group underwent similar, and approximately coeval, diagenetic mineral paragenesis. Furthermore, the diagenetic fluids in these different locations must have been remarkably similar, especially those that produced the delicate APS mineral. Compared to phosphatic cements in the Hornby Bay and Thelon basins, unmineralized sandstone in the Athabasca Basin contains "crandallite group" and fluorapatite cements higher in the basin fill sequence (Wolverine Point Formation) in tuffaceous sandstone and as relatively early cement in the paragenetic sequence.

scholarly journals A Reduced Dose Whole Virion Aluminum Adjuvanted Seasonal Influenza Vaccine Is Immunogenic, Safe, and Well Tolerated in Pediatric Patients

Viruses ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 500
Author(s):  
Zoltan Vajo ◽  
Gergely Balaton ◽  
Peter Vajo ◽  
Peter Torzsa
Keyword(s):  
Pediatric Patients ◽  
Geometric Mean ◽  
Age Groups ◽  
Aluminum Phosphate ◽  
Vaccine Virus ◽  
Serious Adverse Events ◽  
Reduced Dose ◽  
Viral Hemagglutinin ◽  
Virus Strains ◽  
Two Age Groups

Background: Data suggest that pediatric patients might react differently to influenza vaccination, both in terms of immunity and side effects. We have recently shown that using a whole virion vaccine with aluminum phosphate adjuvants, reduced dose vaccines containing 6 µg of viral hemagglutinin (HA) per strain are immunogenic, and well tolerated in adult and elderly patients. Here we show the results of a multicenter clinical trial of pediatric patients, using reduced doses of a new, whole virion, aluminum phosphate adjuvanted vaccine (FluArt, Budapest, Hungary). Methods: A total of 120 healthy volunteers were included in two age groups (3–11 years, receiving 3 µg of HA per strain, and 12–18 years, receiving 6 µg of HA per strain). We used hemagglutination inhibition testing to assess immunogenicity, based on EMA and FDA licensing criteria, including post/pre-vaccination geometric mean titer ratios, seroconversion and seropositivity rates. Safety and tolerability were assessed using CHMP guidelines. Results: All subjects entered the study and were vaccinated (ITT population). All 120 subjects attended the control visit on Day 21 (PP population). All immunogenicity licensing criteria were met in both age groups for all three vaccine virus strains. No serious adverse events were detected and the vaccine was well tolerated by both age groups. Discussion: Using a whole virion vaccine and aluminum phosphate adjuvants, a reduction in the amount of the viral hemmaglutinin is possible while maintaining immunogenicity, safety and tolerability in pediatric and adolescent patients.

A novel separation method of the valuable components for activated clay production wastewater

2021 ◽  
Vol 19 (1) ◽  
pp. 530-540
Author(s):  
Lvshan Zhou ◽  
Tongjiang Peng ◽  
Hongjuan Sun ◽  
Dong Fu ◽  
Chuan Lai
Keyword(s):  
Aluminum Phosphate ◽  
Iron Phosphate ◽  
Acid Sites ◽  
Precipitation Method ◽  
Molar Ratio ◽  
Precipitation Process ◽  
Iron Aluminum ◽  
Phosphorus Iron ◽  
Optimized Conditions ◽  
Acidic Wastewater

Abstract The acidic wastewater produced by the wet production of activated clay contains valuable components such as iron and aluminum. The precipitation method was successfully introduced to separate iron and aluminum from the activated clay production wastewater step by step, which can not only recover the valuable components, but also avoid environmental pollution. In the separation process, gypsum, iron aluminum phosphate, alumina, and sodium sulfate were prepared, and the phase compositions of separation products were analyzed by XRD and IR. The main influencing factors in the separation of iron and aluminum components were studied by single factor experiment. The results show that at the optimized conditions, phosphorus/iron molar ratio 6.0, the system pH 3.0, the reaction temperature 343 K, and the reaction time 90 min, the iron(iii) ion in the system can form a sodium-containing aluminum iron phosphate double salt, and the filtrate after separating Fe3+ and part of Al3+ can meet the requirements for forming high-purity Al2O3. During the phosphate precipitation process, the hypothesis should be correct that Al3+ reacts with PO 4 3 − {\text{PO}}_{4}^{3-} to form an AlPO4 skeleton, Fe3+ isomorphically replaces Al3+ in the [AlO4] tetrahedron, and adsorption occurs simultaneously, with Na+ occupying the terminal acid sites, P(Al)–OH.

Sign in / Sign up

Export Citation Format

Share Document