Removal of Nitric Oxide and Sulfur Dioxide from Flue Gas Using a Hexamminecobalt(II)/Iodide Solution

2004 ◽  
Vol 43 (15) ◽  
pp. 4048-4053 ◽  
Author(s):  
Xiang-li Long ◽  
Wen-de Xiao ◽  
Wei-kang Yuan
2010 ◽  
Vol 24 (9) ◽  
pp. 4931-4936 ◽  
Author(s):  
Yangxian Liu ◽  
Jun Zhang ◽  
Changdong Sheng ◽  
Yongchun Zhang ◽  
Liang Zhao

Author(s):  
Akili D. Khawaji ◽  
Jong-Mihn Wie

The most popular method of controlling sulfur dioxide (SO2) emissions in a steam turbine power plant is a flue gas desulfurization (FGD) process that uses lime/limestone scrubbing. Another relatively newer FGD technology is to use seawater as a scrubbing medium to absorb SO2 by utilizing the alkalinity present in seawater. This seawater scrubbing FGD process is viable and attractive when a sufficient quantity of seawater is available as a spent cooling water within reasonable proximity to the FGD scrubber. In this process the SO2 gas in the flue gas is absorbed by seawater in an absorber and subsequently oxidized to sulfate by additional seawater. The benefits of the seawater FGD process over the lime/limestone process and other processes are; 1) The process does not require reagents for scrubbing as only seawater and air are needed, thereby reducing the plant operating cost significantly, and 2) No solid waste and sludge are generated, eliminating waste disposal, resulting in substantial cost savings and increasing plant operating reliability. This paper reviews the thermodynamic aspects of the SO2 and seawater system, basic process principles and chemistry, major unit operations consisting of absorption, oxidation and neutralization, plant operation and performance, cost estimates for a typical seawater FGD plant, and pertinent environmental issues and impacts. In addition, the paper presents the major design features of a seawater FGD scrubber for the 130 MW oil fired steam turbine power plant that is under construction in Madinat Yanbu Al-Sinaiyah, Saudi Arabia. The scrubber with the power plant designed for burning heavy fuel oil containing 4% sulfur by weight, is designed to reduce the SO2 level in flue gas to 425 ng/J from 1,957 ng/J.


1996 ◽  
Vol 82 (4) ◽  
pp. 351-354 ◽  
Author(s):  
Ken-Ichi Yoshihara ◽  
Hiroyasu Nagase ◽  
Kaoru Eguchi ◽  
Kazumasa Hirata ◽  
Kazuhisa Miyamoto

2019 ◽  
Vol 9 (4) ◽  
pp. 27-32
Author(s):  
Olga A. BALANDINA ◽  
Svetlana M. PURING

The analysis of the values of the concentrations of the formed nitrogen oxides and the temperatures of the jet plume under various conditions of mixture formation is carried out. The plots of the distribution of torch temperatures and concentrations of nitric oxide in the calculated area for oxidizer temperatures of 20, 60, 100, 150, and 200 ° C were obtained and analyzed. Mathematical modeling of the gaseous fuel combustion process was carried out using the FlowVision software package. An analysis of the results showed that a decrease in the temperature of the air supplied as an oxidizing agent leads to a significant decrease in the concentration of nitrogen oxides in flue gases, while not significantly affecting the change in the flame temperature. The research results can be used to solve the problems of optimizing boiler plants, in order to reduce harmful flue gas emissions. Further modeling is planned to determine the dependence of the influence of various factors on the degree of formation of nitrogen oxides in the flue gases of boiler plants.


1979 ◽  
Vol 101 (4) ◽  
pp. 615-619 ◽  
Author(s):  
T. D. Brown ◽  
G. K. Lee ◽  
H. A. Bambrough

A pilot-scale research boiler (750 kg steam/hr) has been used to study the degree of sulphur neutralization during combustion experiments with three lignites. A series of four closely controlled experiments showed that sulphur balances close to 100 percent could be achieved in the pilot-scale system burning Gascoyne lignite; in these experiments the sulphur retained in solid phase residues varied between 21 and 24 percent of the input sulphur. It was also demonstrated with Utility lignite that external recirculation of flue-gas was moderately effective in reducing nitric oxide emissions at the expense of major increased in the carry-over of unburnt carbon. However, sulphur dioxide neutralization by the coal-ash cations remained essentially unchanged as the recirculation ratio increased. Enhancement of sulphur neutralization by dry lime addition to Poplar River lignite was only found to be effective at addition rates above 1/2 percent lime by weight. The effectiveness of the lime was found to increase as the excess-air level increased.


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