scholarly journals Toward a Reactant Library in Template-Directed Solid-State Organic Synthesis:  Reactivity Involving a Monofunctional Reactant Based on a Stilbazole

2002 ◽  
Vol 41 (18) ◽  
pp. 4494-4497 ◽  
Author(s):  
Leonard R. MacGillivray ◽  
Jennifer L. Reid ◽  
John A. Ripmeester ◽  
Giannis S. Papaefstathiou
Keyword(s):  
Solid State ◽  
Organic Synthesis

Organic Synthesis in Solid State

2004 ◽  
pp. 189-231 ◽  
Author(s):  
V. K. Ahluwalia ◽  
M. Kidwai
Keyword(s):  
Solid State ◽  
Organic Synthesis

Discrete and infinite coordination arrays derived from a template-directed, solid-state, organic synthesis

CrystEngComm ◽  
2002 ◽  
Vol 4 (41) ◽  
pp. 223-226 ◽  
Author(s):  
Tamara D. Hamilton ◽  
Giannis S. Papaefstathiou ◽  
Leonard R. MacGillivray
Keyword(s):  
Solid State ◽  
Organic Synthesis

Small heterocycles as highly luminescent building blocks in the solid state for organic synthesis

2016 ◽  
Vol 40 (3) ◽  
pp. 2785-2791 ◽  
Author(s):  
Fabiano da Silveira Santos ◽  
Natália Goedtel Medeiros ◽  
Ricardo Ferreira Affeldt ◽  
Rodrigo da Costa Duarte ◽  
Sidnei Moura ◽  
...  
Keyword(s):  
Solid State ◽  
Organic Synthesis ◽  
Building Blocks ◽  
Synthetic Methodology

ESIPT photoactive mono-formylated benzoxazole derivatives obtained through a Duff functionalization protocol using a simple synthetic methodology.

scholarly journals Multistep Solid-State Organic Synthesis of Carbamate-Linked Covalent Organic Frameworks

2019 ◽  
Vol 141 (28) ◽  
pp. 11253-11258 ◽  
Author(s):  
Steven J. Lyle ◽  
Thomas M. Osborn Popp ◽  
Peter J. Waller ◽  
Xiaokun Pei ◽  
Jeffrey A. Reimer ◽  
...  
Keyword(s):  
Solid State ◽  
Organic Synthesis ◽  
Covalent Organic Frameworks

scholarly journals Precision Nanotube Mimics via Self-Assembly of Programmed Carbon Nanohoops

2019 ◽  
Author(s):  
Jeff M. Van Raden ◽  
Erik Leonhardt ◽  
Lev N. Zakharov ◽  
Andrés Pérez-Guardiola ◽  
Angel Jose Perez Jimenez ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Solid State ◽  
Organic Synthesis ◽  
Self Assembly ◽  
Carbon Nanomaterials ◽  
Weak Interactions ◽  
The Self ◽  
X Ray Crystallography ◽  
Access Structures ◽  
Potential Applications

The scalable production of homogenous, uniform carbon nanomaterials represents a key synthetic challenge for contemporary organic synthesis as nearly all current fabrication methods provide heterogenous mixtures of various carbonized products. For carbon nanotubes (CNTs) in particular, the inability to access structures with specific diameters or chiralities severely limits their potential applications. Here, we present a general approach to access solid-state CNT mimic structures via the self-assembly of fluorinated nanohoops, which can be synthesized in a scalable, size-selective fashion. X-ray crystallography reveals that these CNT mimics exhibit uniform channel diameters that are precisely defined by the diameter of their nanohoop constituents, which self-assemble in a tubular fashion via a combination of arene-pefluoroarene and C—H---F interactions. The nanotube-like assembly of these systems results in capabilities such as linear guest alignment and permanently accessible channels, both of which are observed in CNTs but not in the analogous all-hydrocarbon nanohoop systems. Calculations suggest that the organofluorine interactions observed in the crystal structure are indeed critical in the self-assembly and robustness of the CNT mimic systems. This work establishes the self-assembly of carbon nanohoops via weak interactions as an attractive means to generate solid-state materials that mimic carbon nanotubes, importantly with the unparalleled tunability enabled by organic synthesis. <br>

scholarly journals Precision Nanotube Mimics via Self-Assembly of Programmed Carbon Nanohoops

2019 ◽  
Author(s):  
Jeff M. Van Raden ◽  
Erik Leonhardt ◽  
Lev N. Zakharov ◽  
Andrés Pérez-Guardiola ◽  
Angel Jose Perez Jimenez ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Solid State ◽  
Organic Synthesis ◽  
Self Assembly ◽  
Carbon Nanomaterials ◽  
Weak Interactions ◽  
The Self ◽  
X Ray Crystallography ◽  
Access Structures ◽  
Potential Applications

The scalable production of homogenous, uniform carbon nanomaterials represents a key synthetic challenge for contemporary organic synthesis as nearly all current fabrication methods provide heterogenous mixtures of various carbonized products. For carbon nanotubes (CNTs) in particular, the inability to access structures with specific diameters or chiralities severely limits their potential applications. Here, we present a general approach to access solid-state CNT mimic structures via the self-assembly of fluorinated nanohoops, which can be synthesized in a scalable, size-selective fashion. X-ray crystallography reveals that these CNT mimics exhibit uniform channel diameters that are precisely defined by the diameter of their nanohoop constituents, which self-assemble in a tubular fashion via a combination of arene-pefluoroarene and C—H---F interactions. The nanotube-like assembly of these systems results in capabilities such as linear guest alignment and permanently accessible channels, both of which are observed in CNTs but not in the analogous all-hydrocarbon nanohoop systems. Calculations suggest that the organofluorine interactions observed in the crystal structure are indeed critical in the self-assembly and robustness of the CNT mimic systems. This work establishes the self-assembly of carbon nanohoops via weak interactions as an attractive means to generate solid-state materials that mimic carbon nanotubes, importantly with the unparalleled tunability enabled by organic synthesis. <br>

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