Kinetics of phase-transfer catalytic esterification of phthalic acid monobutyl ester

1988 ◽  
Vol 27 (9) ◽  
pp. 1582-1587 ◽  
Author(s):  
Mou Yung Yeh ◽  
Huei Horng Guo ◽  
Lai Cheng Chen ◽  
Yen Ping Shih
Keyword(s):  
Phthalic Acid ◽  
Phase Transfer ◽  
Kinetics Of

Effects of salts on the kinetics of oxidation of alkenes by thallic salts in aqueous solutions

1981 ◽  
Vol 46 (3) ◽  
pp. 693-700 ◽  
Author(s):  
Milan Strašák ◽  
Jaroslav Majer
Keyword(s):  
Aqueous Solutions ◽  
Phase Transfer ◽  
Heterogeneous Reaction ◽  
Qualitative Model ◽  
Kinetic Effect ◽  
Tetraalkylammonium Salts ◽  
Reaction Conditions ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Heterogeneous Reaction Conditions

The kinetics of oxidation of alkenes by thallic sulphate in aqueous solutions, involving the two reaction steps-the hydroxythallation and the dethallation - was studied, and the effect of salts on the kinetics was examined; this made it possible to specify more precisely the reaction mechanism and to suggest a qualitative model of the reaction coordinate. It was found that in homogeneous as well as in heterogeneous reaction conditions, the reaction can be accelerated appreciably by adding tetraalkylammonium salts. These salts not only operate as catalysts of the phase transfer, but also exert a significant kinetic effect, which can be explained with a simplification in terms of a stabilization of the transition state of the reaction.

Phase-Transfer Catalytic Kinetics of the Synthesis of Phenyl Benzoate

1995 ◽  
Vol 34 (5) ◽  
pp. 1572-1580 ◽  
Author(s):  
Yao-Sheng Lee ◽  
Mou-Yung Yeh ◽  
Yen-Ping Shih
Keyword(s):  
Phase Transfer ◽  
Phenyl Benzoate ◽  
Catalytic Kinetics ◽  
Kinetics Of

Kinetics of a Phase-Transfer Catalysis Reaction in Supercritical Fluid Carbon Dioxide

1996 ◽  
Vol 35 (6) ◽  
pp. 1801-1806 ◽  
Author(s):  
Angela K. Dillow ◽  
S. L. Jimmy Yun ◽  
David Suleiman ◽  
David L. Boatright ◽  
Charles L. Liotta ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Fluid ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Supercritical Fluid Carbon Dioxide ◽  
Kinetics Of
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