Separation of isomers using retrograde crystallization from supercritical fluids

1987 ◽  
Vol 26 (11) ◽  
pp. 2372-2377 ◽  
Author(s):  
Keith P. Johnston ◽  
Stephen E. Barry ◽  
Nolan K. Read ◽  
Tyler R. Holcomb
Keyword(s):  
Supercritical Fluids ◽  
Separation Of Isomers

FLUID PROPERTY VARIATION ANALYSIS IN A HEAT EXCHANGER USING SUPERCRITICAL FLUIDS

2020 ◽  
Author(s):  
K H Jyothiprakash ◽  
Agniv Saha ◽  
Arihant Kumar Patawari ◽  
K. N. Seetharamu
Keyword(s):  
Heat Exchanger ◽  
Supercritical Fluids ◽  
Variation Analysis ◽  
Property Variation ◽  
Fluid Property

Monomethyl and dimethyl ethers of methyl β-D-xylopyranoside

1984 ◽  
Vol 49 (12) ◽  
pp. 2922-2931 ◽  
Author(s):  
Jan Staněk ◽  
Jana Jeřábková ◽  
Jiří Jarý
Keyword(s):  
Partial Methylation ◽  
Separation Of Isomers ◽  
Subsequent Separation ◽  
Single Reaction

The preparative advantages of partial methylation with subsequent separation of isomers over standard syntheses of individual derivatives are presented on the case of the methylation of methyl β-D-xylopyranoside (I). All seven possible methyl ethers were isolated in reasonable yields from a single reaction. Literature data concerning methyl 2,3-di-O-methyl-β-D-xylopyranoside (V) and methyl 2,4-di-O-methyl-β-D-xylopyranoside (VI) have been revised.

scholarly journals A crossover of the solid substances solubility in supercritical fluids: what is it in fact?

2021 ◽  
pp. 115997
Author(s):  
N.N. Kalikin ◽  
R.D. Oparin ◽  
A.L. Kolesnikov ◽  
Y.A. Budkov ◽  
M.G. Kiselev
Keyword(s):  
Supercritical Fluids

scholarly journals F/OH ratio in a rare fluorine-poor blue topaz from Padre Paraíso (Minas Gerais, Brazil) to unravel topaz’s ambient of formation

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
N. Precisvalle ◽  
A. Martucci ◽  
L. Gigli ◽  
J. R. Plaisier ◽  
T. C. Hansen ◽  
...  
Keyword(s):  
Supercritical Fluids ◽  
Fluorine Content ◽  
Minas Gerais ◽  
Hydroxyl Groups ◽  
Exchange Reactions ◽  
Silicate System ◽  
Mullite Phase ◽  
Anomalous Water

AbstractTopaz [Al2SiO4(F,OH)2] is one of the main fluorine-bearing silicates occurring in environments where variably acidic (F)/aqueous (OH) fluids saturate the silicate system. In this work we fully characterized blue topaz from Padre Paraíso (Minas Gerais, Brazil) by means of in situ synchrotron X-Ray and neutron powder diffraction measurements (temperature range 298–1273 K) combined with EDS microanalyses. Understanding the role of OH/F substitution in topaz is important in order to determine the hydrophilicity and the exchange reactions of fluorine by hydroxyl groups, and ultimately to characterize the environmental redox conditions (H2O/F) required for mineral formation. The fluorine content estimated from neutron diffraction data is ~ 1.03 a.f.u (10.34 wt%), in agreement with the chemical data (on average 10.0 wt%). The XOH [OH/(OH + F)] (0.484) is close to the maximum XOH value (0.5), and represents the OH- richest topaz composition so far analysed in the Minas Gerais district. Topaz crystallinity and fluorine content sharply decrease at 1170 K, while mullite phase starts growing. On the basis of this behaviour, we suggest that this temperature may represent the potential initial topaz’s crystallization temperature from supercritical fluids in a pegmatite system. The log(fH2O/fHF)fluid (1.27 (0.06)) is coherent with the fluorine activity calculated for hydrothermal fluids (pegmatitic stage) in equilibrium with the forming mineral (log(fH2O/fHF)fluid = 1.2–6.5) and clearly different from pure magmatic (granitic) residual melts [log(fH2O/fHF)fluid < 1]. The modelled H2O saturated fluids with the F content not exceeding 1 wt% may represent an anomalous water-dominant / fluorine-poor pegmatite lens of the Padre Paraíso Pegmatite Field.

Astaxanthin Extraction from Marine Crustacean Waste Streams: An Integrate Approach between Microwaves and Supercritical Fluids

2021 ◽  
Vol 9 (8) ◽  
pp. 3050-3059 ◽  
Author(s):  
Ana N. Nunes ◽  
Ana Roda ◽  
Luís F. Gouveia ◽  
Naiara Fernández ◽  
Maria Rosário Bronze ◽  
...  
Keyword(s):  
Supercritical Fluids ◽  
Integrate Approach ◽  
Waste Streams ◽  
Marine Crustacean ◽  
Astaxanthin Extraction
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