Hydrogen-atom-induced substitution reaction of organic sulfur compounds in the gas phase

1992 ◽  
Vol 31 (1) ◽  
pp. 8-13 ◽  
Author(s):  
Muneyoshi Yamada ◽  
Akira Amano
Keyword(s):  
Hydrogen Atom ◽  
Gas Phase ◽  
Substitution Reaction ◽  
Sulfur Compounds ◽  
Organic Sulfur ◽  
Organic Sulfur Compounds

Sulfur isotopic composition of gas-phase organic sulfur compounds provides insights into the thermal maturation of organic-rich rocks

2019 ◽  
Vol 259 ◽  
pp. 91-108 ◽  
Author(s):  
Alon Amrani ◽  
Yoav Oved Rosenberg ◽  
Alexander Meshoulam ◽  
Ward Said-Ahmad ◽  
Courtney Turich ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Gas Phase ◽  
Sulfur Compounds ◽  
Organic Sulfur ◽  
Sulfur Isotopic Composition ◽  
Thermal Maturation ◽  
Organic Sulfur Compounds

scholarly journals Pollution status of volatile organic sulfur compounds causing odor in Xi River and factors influencing spatial distribution

2020 ◽  
Vol 20 (4) ◽  
pp. 1264-1270
Author(s):  
Xiang Tu ◽  
Shaohua Chen ◽  
Siyu Wang ◽  
Haiqing Liao ◽  
Xuejiao Deng
Keyword(s):  
Spatial Distribution ◽  
Sulfur Compounds ◽  
Organic Sulfur ◽  
Industrial Emissions ◽  
Diethyl Sulfide ◽  
Organic Sulfur Compounds ◽  
Factors Influencing ◽  
Pollution Status ◽  
Volatile Organic ◽  
Volatile Organic Sulfur Compounds

Abstract This study investigated the pollution status of volatile organic sulfur compounds (VOSCs) and the factors influencing their spatial distribution in the Xi River in Shenyang, China. A method for simultaneous determination of 14 VOSCs that cause odor in water samples was developed by using purge and trap coupled with gas chromatography and a flame photometric detector. The results indicated that each target compound could be identified from 15 sampling sites, and the total concentration of 14 VOSCs ranged from 2.575 to 52.981 μg L−1. Dimethyl sulfide (DMS) was the most important contaminant with an average concentration of 4.029 μg L−1, a detection rate of 93.33% and a variation coefficient of 0.72. The VOSCs were primarily distributed in suburban and rural sections, and the suburban section was the worst in regard to pollution by VOSCs. Dimethyl trisulfide was primarily distributed in urban and suburban sections of the Xi River due to industrial emissions. Ethanethiol, DMS, and ethyl methyl sulfide, which are typical by-products of microbial anaerobic decomposition from domestic wastewater, were found in abundance in the suburban section. Diethyl sulfide, diethyl disulfide, methyl propyl disulfide, and 1-propyl disulfide representing agricultural nonpoint source pollution were mostly distributed in the rural section.

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