Metal Pyrazolato Complexes. Synthesis, Characterization, and X-ray Powder Diffraction Studies of Group 12 Coordination Polymers

1999 ◽  
Vol 38 (16) ◽  
pp. 3657-3664 ◽  
Author(s):  
Norberto Masciocchi ◽  
G. Attilio Ardizzoia ◽  
Angelo Maspero ◽  
Girolamo LaMonica ◽  
Angelo Sironi
Keyword(s):  
Powder Diffraction ◽  
Coordination Polymers ◽  
X Ray ◽  
Group 12

Synthesis, Solid-State NMR, and X-ray Powder Diffraction Characterization of Group 12 Coordination Polymers, Including the First Example of a C-Mercuriated Pyrazole

2006 ◽  
Vol 45 (22) ◽  
pp. 9064-9074 ◽  
Author(s):  
Norberto Masciocchi ◽  
Simona Galli ◽  
Enrica Alberti ◽  
Angelo Sironi ◽  
Corrado Di Nicola ◽  
...  
Keyword(s):  
Solid State ◽  
Powder Diffraction ◽  
Coordination Polymers ◽  
Solid State Nmr ◽  
X Ray ◽  
Group 12

Synthesis and characterization of 2-aminobenzoimidazolate group 11 coordination polymers: A combined X-ray powder diffraction and 13CP MAS NMR study

2008 ◽  
Vol 11 (5) ◽  
pp. 502-505 ◽  
Author(s):  
G. Attilio Ardizzoia ◽  
Stefano Brenna ◽  
Fulvio Castelli ◽  
Simona Galli ◽  
Norberto Masciocchi ◽  
...  
Keyword(s):  
Powder Diffraction ◽  
Coordination Polymers ◽  
Mas Nmr ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Nmr Study

Enclosing the functional properties of pyrazolato-based coordination polymers within a structural frame: the role of laboratory X-ray powder diffraction

2013 ◽  
Vol 28 (S2) ◽  
pp. S106-S125 ◽  
Author(s):  
Simona Galli ◽  
Norberto Masciocchi
Keyword(s):  
Functional Properties ◽  
Powder Diffraction ◽  
Coordination Polymers ◽  
Laboratory Data ◽  
Recent Experience ◽  
Structural Description ◽  
X Ray ◽  
Physico Chemical ◽  
Metal Bonds

Ab initio X-ray powder diffraction structural analyses from laboratory data have been widely employed in the characterization of coordination polymers not affording single crystals of suitable quality to undergo conventional structural determinations. This is particularly true for coordination polymers built upon strong ligand-to-metal bonds, as those formed by anionic, nitrogen-based heterocycles - pyrazolates, imidazolates, pyrimidinolates and more complex moieties derived therefrom. More than one hundred species belonging to this class have been structurally characterized in the last three decades, affording key, otherwise inaccessible stereochemical and supramolecolar features. This contribution summarizes our most recent experience in the XRPD structural characterization of pyrazolato-based coordination polymers, devoting a special consideration to the methodologies and tricks which allowed us to juxtapose the structural description of these materials to their physico-chemical and, above all, functional properties.

Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine

2001 ◽  
Vol 56 (10) ◽  
pp. 997-1002 ◽  
Author(s):  
Chnstian Näther ◽  
Inke Jeß ◽  
Harald Studzinski
Keyword(s):  
Thermal Analysis ◽  
Thermal Decomposition ◽  
Differential Thermal Analysis ◽  
Thermal Behaviour ◽  
Powder Diffraction ◽  
Coordination Polymers ◽  
Intermediate Phase ◽  
Compound I ◽  
X Ray

The thermal behaviour of the three coordination polymers 2∞poly[CuX(μ-2-methylpyrazine- N,N′)] (X = Cl (I), Br (II)), and 2∞poly[{Cu2l2 (μ-pyrazine-N,N′)2 } · 2-methylpyrazine] (III) was investigated using differential thermal analysis and thermogravimetry (DTA-TG) measurements as well as temperature resolved X-ray powder diffraction in argon and in air. On heating all compounds decompose in two steps. In the first step compound I and II loose one and compound III looses two of the 2-methylpyrazine ligands to form the corresponding 2:1 compounds Cu2Cl2(2 -methylpyrazine) (IV) and 2∞poly[Cu2X2 (μ-2 -methylpyrazine-N,N′)] (X = Br (V), I (VI)). From the experiments there is no evidence for the formation of a 1:1 compound of Cul and 2-methylpyrazine as an intermediate phase during the thermal decomposition. On further heating the 2:1 compounds IV, V and VI transform directly to the corresponding copper(I) halides.

Metal Imidazolato Complexes:  Synthesis, Characterization, and X-ray Powder Diffraction Studies of Group 10 Coordination Polymers

2001 ◽  
Vol 40 (27) ◽  
pp. 6983-6989 ◽  
Author(s):  
Norberto Masciocchi ◽  
G. Attilio Ardizzoia ◽  
Girolamo LaMonica ◽  
Angelo Maspero ◽  
Simona Galli ◽  
...  
Keyword(s):  
Powder Diffraction ◽  
Coordination Polymers ◽  
X Ray ◽  
Group 10
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