β-K4La6I14Os:  A New Structure Type for Rare-Earth-Metal Cluster Compounds That Contains Discrete Tetrahedral K4I3+Units

1999 ◽  
Vol 38 (17) ◽  
pp. 3831-3835 ◽  
Author(s):  
S. Uma ◽  
John D. Corbett
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Metal Cluster ◽  
Earth Metal ◽  
Structure Type ◽  
Cluster Compounds

ChemInform Abstract: The (Th12N6X41)13- Cluster: An Extension of Rare Earth Metal Cluster Chemistry.

ChemInform ◽  
2010 ◽  
Vol 27 (30) ◽  
pp. no-no
Author(s):  
T. P. BRAUN ◽  
A. SIMON ◽  
F. UENO ◽  
F. BOETTCHER
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Metal Cluster ◽  
Earth Metal ◽  
Cluster Chemistry

scholarly journals Rare-earth Metal Borosilicides R 9 Si15-x B3 (R = Tb, Yb): New Ordered Structures Derived from the AlB2 Structure Type

2020 ◽  
Vol 646 (14) ◽  
pp. 1168-1175
Author(s):  
Volodymyr Babizhetskyy ◽  
Volodymyr Levytskyi ◽  
Régis Jardin ◽  
Josef Bauer ◽  
Roland Guérin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structure Type ◽  
Ordered Structures

scholarly journals Representatives of the structure type Sc2Re3Si4inR−{Ti, Zr,Hf}−Si systems (R– rare-earth metal)

2014 ◽  
pp. 128-133
Author(s):  
N.M. Muts ◽  
◽  
Ya.O. Tokaychuk ◽  
M.O. Boyko ◽  
P.Yu. Demchenko ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structure Type

Flux synthesis, crystal structure and electronic properties of the layered rare earth metal boride silicide Er3Si5–x B. An example of a boron/silicon-ordered structure derived from the AlB2 structure type

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Volodymyr Babizhetskyy ◽  
Régis Jardin ◽  
Régis Gautier ◽  
Bruno Fontaine ◽  
Jean-François Halet
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Density Functional ◽  
Earth Metal ◽  
Structure Type ◽  
Metal Boride ◽  
Ordered Structure ◽  
Flux Synthesis ◽  
Bonding Properties ◽  
Difference Fourier

Abstract The ternary rare earth metal boride silicide Er3Si5–x B (x = 1.17) was synthesized from the elements using the tin flux method. It crystallizes in a new structure type in the space group R32 (a = 6.5568(1) Å, c = 24.5541(1) Å, Z = 6). The structural arrangement can be derived from the AlB2 structure type with boron/silicon ordering in the layered metalloid substructure made of [Si5B] hexagons. The presence or absence of the boron atoms involved in this ordered structure is discussed on the basis of difference Fourier syntheses and structural analysis, in relation with the binary parent structures AlB2 and Yb3Si5 (Th3Pd5 type). The electronic and bonding properties of Er3Si5–x B were analyzed and discussed via density functional theory (DFT) calculations and a crystal orbital Hamiltonian population (COHP) bonding analysis.

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