Activation of Carbon Dioxide:  Gas-Phase Reactions of Y+, YO+, and YO2+with CO and CO2

1999 ◽  
Vol 38 (2) ◽  
pp. 397-402 ◽  
Author(s):  
M. R. Sievers ◽  
P. B. Armentrout
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Gas Phase Reactions ◽  
Carbon Dioxide Gas

ChemInform Abstract: GAS PHASE REACTIONS OF ANIONS WITH NITROUS OXIDE AND CARBON DIOXIDE

1977 ◽  
Vol 8 (47) ◽  
pp. no-no
Author(s):  
V. M. BIERBAUM ◽  
C. H. DEPUY ◽  
R. H. SHAPIRO
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Gas Phase ◽  
Gas Phase Reactions

Gas-Phase Reactions of Carbon Dioxide with Copper Hydride Anions Cu2H2–: Temperature-Dependent Transformation

2018 ◽  
Vol 122 (34) ◽  
pp. 19379-19384 ◽  
Author(s):  
Yun-Zhu Liu ◽  
Li-Xue Jiang ◽  
Xiao-Na Li ◽  
Li-Na Wang ◽  
Jiao-Jiao Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Copper Hydride ◽  
Gas Phase Reactions ◽  
Temperature Dependent

Nb2BN2− cluster anions reduce four carbon dioxide molecules: reactivity enhancement by ligands

2020 ◽  
Vol 49 (40) ◽  
pp. 14081-14087 ◽  
Author(s):  
Hai-Yan Zhou ◽  
Ming Wang ◽  
Yong-Qi Ding ◽  
Jia-Bi Ma
Keyword(s):  
Mass Spectrometry ◽  
Carbon Dioxide ◽  
Density Functional Theory ◽  
Gas Phase ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Cluster Anions ◽  
Gas Phase Reactions ◽  
Functional Theory ◽  
Flight Mass Spectrometry

The thermal gas-phase reactions of Nb2BN2− cluster anions with carbon dioxide have been explored by using the art of time-of-flight mass spectrometry and density functional theory calculations.

Mathematical Modeling of Heat and Mass Transfer Processes During Pyrolysis and Combustion of a Single Biomass Particle

2012 ◽  
Author(s):  
Y. Haseli ◽  
J. A. van Oijen ◽  
L. P. H. de Goey
Keyword(s):  
Carbon Dioxide ◽  
Mass Transfer ◽  
Carbon Monoxide ◽  
Water Vapor ◽  
Gas Phase ◽  
Combustion Process ◽  
Combustion Model ◽  
Gas Phase Reactions ◽  
Transfer Processes ◽  
Mass Transfer Processes

A detailed mathematical model is developed for simulation of heat and mass transfer processes during the pyrolysis and combustion of a single biomass particle. The kinetic scheme of Shafizadeh and Chin is employed to describe the pyrolysis process. The light gases formed during the biomass pyrolysis is assumed to consist of methane, carbon dioxide, carbon monoxide, hydrogen and water vapor with given mass fractions relevant to those found in the experiments of high heating conditions. The combustion model takes into account the reactions of oxygen with methane, hydrogen, carbon monoxide, tar and char as well as gasification of char with water vapor and carbon dioxide. Appropriate correlations taken from past studies are used for computation of the rate of these reactions. The model allows calculation of time and space evolution of various parameters including biomass and char densities, gaseous species and temperature. Different experimental data reported in the literature are employed to validate the pyrolysis and combustion models. The reasonable agreement obtained between the predictions and measured data reveals that the presented model is capable of successfully capturing various experiments of wood particle undergoing a pyrolysis or combustion process. In particular, the role of gas phase reactions within and adjacent to particle on the combustion process is examined. The results indicate that for the case of small particles in the order of millimeter size and less, one may neglect any effects of gas phase reactions. However, for larger particles, a combustion model may need to include hydrogen oxidation and even carbon monoxide combustion reactions.

Gas phase reactions of anions with nitrous oxide and carbon dioxide

1977 ◽  
Vol 99 (17) ◽  
pp. 5800-5802 ◽  
Author(s):  
Veronica M. Bierbaum ◽  
C. H. DePuy ◽  
R. H. Shapiro
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Gas Phase ◽  
Gas Phase Reactions
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