Reactivity of Hydrides FeH2(CO)2P2(P = Phosphites) with Aryldiazonium Cations:  Preparation, Characterization, X-ray Crystal Structure, and Electrochemical Studies of Mono- and Binuclear Aryldiazenido Complexes

1998 ◽  
Vol 37 (21) ◽  
pp. 5602-5610 ◽  
Author(s):  
Gabriele Albertin ◽  
Stefano Antoniutti ◽  
Alessia Bacchi ◽  
Davide Barbera ◽  
Emilio Bordignon ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electrochemical Studies ◽  
X Ray

X-ray crystal structure, EPR and electrochemical studies of two novel cyanonitrosylrhenates: K2[Re(NO)(CN)5]·(Phen)6·4.5H2O and K[Re(NO)(H2O)(CN)4]·(Phen)5·CH3OH·3H2O

2005 ◽  
Vol 8 (1) ◽  
pp. 61-64 ◽  
Author(s):  
Sujoy RoyChowdhury ◽  
Subhajit Dinda ◽  
Santu Chakraborty ◽  
Corine Simonnet ◽  
Alok K. Mukherjee ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electrochemical Studies ◽  
X Ray

scholarly journals Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies

2013 ◽  
Vol 34 (10) ◽  
pp. 3093-3097 ◽  
Author(s):  
Khaled Ghasemi ◽  
Ali Reza Rezvani ◽  
Ibrahim Abdul Razak ◽  
Abolghasem Moghimi ◽  
Fatemeh Ghasemi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Dipicolinic Acid ◽  
Acid Synthesis ◽  
Electrochemical Studies ◽  
X Ray

Binuclear Iron and Ruthenium Complexes with Bis(diazene) or Bis(diazenido) Bridging Ligands:  Synthesis, Characterization, X-ray Crystal Structure, and Electrochemical Studies

1996 ◽  
Vol 35 (21) ◽  
pp. 6245-6253 ◽  
Author(s):  
Gabriele Albertin ◽  
Stefano Antoniutti ◽  
Alessia Bacchi ◽  
Emilio Bordignon ◽  
Giancarlo Pelizzi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Ruthenium Complexes ◽  
Electrochemical Studies ◽  
Bridging Ligands ◽  
X Ray ◽  
Binuclear Iron

The synthesis and characterization of the pendant-armed ligand N,N′-bis(2′-pyridylmethyl)-1,7-dithia-4,11-diazacyclotetradecane (L4) and crystal structures of L4 and the copper(II) complex [Cu(L4)](ClO4)2 — Crystal structure of the nickel(II) complex of N-(2′-pyridylmethyl)-1,4,7-trithia-11-azacyclotetradecane (L2), [Ni(L2)(CH3CN)](ClO4)2·CH3CN

2006 ◽  
Vol 84 (2) ◽  
pp. 187-195 ◽  
Author(s):  
B CM Chak ◽  
A McAuley
Keyword(s):  
Crystal Structure ◽  
Copper Ion ◽  
Esr Spectra ◽  
Synthesis And Characterization ◽  
Electrochemical Studies ◽  
High Dilution ◽  
Donor Ligand ◽  
X Ray ◽  
Distorted Octahedral

The synthesis and characterization of the mixed donor ligand N,N′-bis(2′-pyridylmethyl)-1,7-dithia-4,11-diazacyclotetradecane (L4) containing two pendant pyridine arms is described. The macrocycle formation involves reaction of N-tosylbis(2-bromoethyl)amine with N-tosylbis(3-mercaptopropyl)amine at high dilution followed by detosylation at the nitrogen atoms using LiAlH4 in view of the presence of the thioether groups. An X-ray study of the ligand shows the sulphur atoms lie exo to the macrocyclic ring. The nickel(II) and copper(II) complexes of L4 have been characterized and the X-ray structure of the Cu(II) ion exhibits a five-coordinate copper ion despite the presence of six available donor atoms. In the case of ligand N-(2-pyridylmethyl)-1,4,7-trithia-11-azacyclotetradecane (L2), with a single pendant N donor, the Ni(II) complex is distorted octahedral with a molecule of acetonitrile in the sixth site. Details of UV–vis, ESR spectra, and electrochemical studies on the complexes are presented.Key words: synthesis, pendant-armed, mixed donor S,N macrocycles, copper, nickel.

Synthesis, Characterisation and Crystal Structure of a Copper(II) Dichromate Complex with the N,N’-Bis(2-pyridylmethylene)butane- 1,4-diamine Schiff Base Ligand

2007 ◽  
Vol 62 (4) ◽  
pp. 495-500 ◽  
Author(s):  
Brajagopal Samanta ◽  
Joy Chakraborty ◽  
Shyamapada Shit ◽  
Stuart R. Batten ◽  
Paul Jensen ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Electrochemical Studies ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
X Ray ◽  
Cell Parameters ◽  
Oxygen Donor ◽  
Elemental Analyses

The new complex Cu[L1]Cr2O7has been synthesised with the N,N′-bis(2-pyridylmethylene) butane-1,4-diamine Schiff base L1, [NC5H4CH=N(CH2)4N=CHC5H4N], and characterised with elemental analyses and different spectroscopic and electrochemical studies. The structure of the new complex has been established by single crystal X-ray diffraction. The complex crystallises in the monoclinic system with space group P21/c having cell parameters a = 14.7(5), b = 9.22(2), c = 16.2(5) Å , β = 116.9(1)°, and Z = 4. The Cr2O72− unit is bonded through one terminal oxygen donor end to the central Cu(II) chelated by the Schiff base ligand.

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