Cyanoisocyanoarene Metal Complexes as Building Blocks for Coordination Polymers:  Structural Nonrigidity of a Metal−Nitrile Linkage1

1998 ◽  
Vol 37 (22) ◽  
pp. 5776-5780 ◽  
Author(s):  
Andreas Mayr ◽  
Li-Feng Mao
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Building Blocks ◽  
Structural Nonrigidity

Metal Complexes of Cinchonine as Chiral Building Blocks: A Strategy for the Construction of Nanotubular Architectures and Helical Coordination Polymers

2009 ◽  
Vol 131 (15) ◽  
pp. 5393-5395 ◽  
Author(s):  
Tomasz Kaczorowski ◽  
Iwona Justyniak ◽  
Teodozja Lipińska ◽  
Janusz Lipkowski ◽  
Janusz Lewiński
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Building Blocks

Spin Crossover in a Series of Non-Hofmann-Type Fe(II) Coordination Polymers Based on [Hg(SeCN)3]− or [Hg(SeCN)4]2– Building Blocks

2021 ◽  
Author(s):  
Tong Cao ◽  
Francisco Javier Valverde-Muñoz ◽  
Xiaoyi Duan ◽  
Mingjian Zhang ◽  
Ping Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Spin Crossover ◽  
Building Blocks

2,2':6',2''-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers

2001 ◽  
Vol 121 (1-3) ◽  
pp. 1249-1252 ◽  
Author(s):  
U.S. Schubert ◽  
C. Eschbaumer ◽  
P. Andres ◽  
H. Hofmeier ◽  
C.H. Weidl ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Building Blocks ◽  
Supramolecular Assemblies

Directed adenine functionalization for creating complex architectures for material and biological applications

2017 ◽  
Vol 53 (35) ◽  
pp. 4748-4758 ◽  
Author(s):  
Balaram Mohapatra ◽  
Pratibha Pratibha ◽  
Sandeep Verma
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Bioactive Molecules ◽  
Biological Applications ◽  
Design Strategies ◽  
Feature Article ◽  
Complex Architectures ◽  
Adenine Derivatives

This feature article outlines design strategies for modified adenine derivatives to construct discrete metal complexes, ring-expanded skeletons, coordination polymers, MOFs, and capped nanoparticles, for applications in gas adsorption, as bioimaging agents and as bioactive molecules.

1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes

2009 ◽  
Vol 38 (6) ◽  
pp. 1690 ◽  
Author(s):  
Gianluca Accorsi ◽  
Andrea Listorti ◽  
K. Yoosaf ◽  
Nicola Armaroli
Keyword(s):  
Metal Complexes ◽  
Building Blocks

Symmetrical tetra-β″-sulfoleno-meso-aryl-porphyrins — synthesis, spectroscopy and structural characterization

2014 ◽  
Vol 18 (01n02) ◽  
pp. 115-122 ◽  
Author(s):  
Srinivas Banala ◽  
Klaus Wurst ◽  
Bernhard Kräutler
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Structural Characterization ◽  
Building Blocks ◽  
Cycloaddition Reactions ◽  
One Pot

We report here the preparation (in "one-pot") of a tetra-β″-sulfoleno-meso-aryl-porphyrin in about 80% yield by using an optimized modification of Lindsey's variant of the Adler–Longo approach. The Zn ( II )-, Cu ( II )- and Ni ( II )-complexes of the symmetrical porphyrin were prepared and characterized spectroscopically. Crystal structures of the fluorescent Zn ( II )- and of the non-fluorescent Ni ( II )-tetra-β″-sulfoleno-meso-aryl-porphyrinates showed the highly substituted porphyrin ligands to be nearly perfectly planar. The Zn ( II )-complex of this porphyrin has been used as a thermal precursor of a reactive diene, and — formally — of lateral and diagonal bis-dienes, of a tris-diene and of a tetra-diene, which all underwent [4 + 2]-cycloaddition reactions in situ with a range of dienophiles. Thus, the tetra-β″-sulfoleno-meso-aryl-porphyrin and its metal complexes represent reactive building blocks, "programmed" for the syntheses of symmetrical and highly functionalized porphyrins.

Sign in / Sign up

Export Citation Format

Share Document