Coordination Compounds of Schiff-Base Ligands Derived from Diaminomaleonitrile (DMN):  Mononuclear, Dinuclear, and Macrocyclic Derivatives

1996 ◽  
Vol 35 (19) ◽  
pp. 5492-5499 ◽  
Author(s):  
Mark J. MacLachlan ◽  
Murray K. Park ◽  
Laurence K. Thompson
Keyword(s):  
Schiff Base ◽  
Coordination Compounds ◽  
Schiff Base Ligands

scholarly journals Solid-state supramolecular architectures of a series of Hg(ii) halide coordination compounds based on hydroxyl-substituted Schiff base ligands

CrystEngComm ◽  
2019 ◽  
Vol 21 (41) ◽  
pp. 6301-6312 ◽  
Author(s):  
Taraneh Hajiashrafi ◽  
Shiva Salehi ◽  
Maciej Kubicki ◽  
Antonio Bauzá ◽  
Antonio Frontera ◽  
...  
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Coordination Compounds ◽  
Theoretical Calculations ◽  
Schiff Base Ligands ◽  
Supramolecular Architectures

Herein, six Hg(ii) coordination compounds containing Schiff base ligands were synthesized, characterized and studied using geometrical and Hirshfeld analyses as well as theoretical calculations.

Highly cytotoxic DNA-interacting copper(ii) coordination compounds

Metallomics ◽  
2014 ◽  
Vol 6 (10) ◽  
pp. 1853-1868 ◽  
Author(s):  
Rosa F. Brissos ◽  
Ester Torrents ◽  
Francyelli Mariana dos Santos Mello ◽  
Wanessa Carvalho Pires ◽  
Elisângela de Paula Silveira-Lacerda ◽  
...  
Keyword(s):  
Schiff Base ◽  
Cell Lines ◽  
Cancer Cell ◽  
Coordination Compounds ◽  
Copper Complexes ◽  
Cancer Cell Lines ◽  
Schiff Base Ligands ◽  
High Cytotoxicity

Copper complexes from Schiff-base ligands show high cytotoxicity against diverse cancer cell lines, with IC50 values down to 0.23 μM.

scholarly journals Homo- and Hetero-Oligonuclear Complexes of Platinum Group Metals (PGM) Coordinated by Imine Schiff Base Ligands

2020 ◽  
Vol 21 (10) ◽  
pp. 3493 ◽  
Author(s):  
Barbara Miroslaw
Keyword(s):  
Schiff Base ◽  
Hybrid Materials ◽  
Coordination Compounds ◽  
Catalytic Properties ◽  
Platinum Group Metals ◽  
Schiff Base Ligands ◽  
Polynuclear Species ◽  
Platinum Group ◽  
Construction Strategies ◽  
Imine Ligands

Chemistry of Schiff base (SB) ligands began in 1864 due to the discovery made by Hugo Schiff (Schiff, H., Justus Liebigs Ann. der Chemie 1864, 131 (1), 118–119). However, there is still a vivid interest in coordination compounds based on imine ligands. The aim of this paper is to review the most recent concepts on construction of homo- and hetero-oligonuclear Schiff base coordination compounds narrowed down to the less frequently considered complexes of platinum group metals (PGM). The combination of SB and PGM in oligonuclear entities has several advantages over mononuclear or polynuclear species. Such complexes usually exhibit better electroluminescent, magnetic and/or catalytic properties than mononuclear ones due to intermetallic interactions and frequently have better solubility than polymers. Various construction strategies of oligodentate imine ligands for coordination of PGM are surveyed including simple imine ligands, non-innocent 1,2-diimines, chelating imine systems with additional N/O/S atoms, classic N2O2-compartmental Schiff bases and their modifications resulting in acyclic fused ligands, macrocycles such as calixsalens, metallohelical structures, nano-sized molecular wheels and hybrid materials incorporating mesoionic species. Co-crystallization and formation of metallophilic interactions to extend the mononuclear entities up to oligonuclear coordination species are also discussed.

scholarly journals Spectroscopic behaviour of lanthanide(III) coordination compounds with Schiff base ligands

2000 ◽  
Vol 2 (17) ◽  
pp. 3753-3757 ◽  
Author(s):  
Koen Binnemans ◽  
Rik Van Deun ◽  
Christiane Görller-Walrand ◽  
Simon R. Collinson ◽  
Françoise Martin ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Compounds ◽  
Schiff Base Ligands ◽  
Spectroscopic Behaviour

Conductivity Studies of Schiff Base Ligands Derived from O-Phenylenediamine and Their Co(II) and Zn(II) Complexes

2015 ◽  
Vol 12 (2) ◽  
pp. 13
Author(s):  
Muhamad Faridz Osman ◽  
Karimah Kassim
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Schiff Base ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Impedance Spectroscopy ◽  
Ftir Spectroscopy ◽  
Coordination Complexes ◽  
Frequency Range ◽  
Schiff Base Ligands

The coordination complexes of Co(II) and Zn(II) with Schiff bases derived from o-phenylenediamine and substituted 2-hydroxybenzaldehyde were prepared All compounds were characterized by Fourier transform infrared (FTIR) spectroscopy and Nuclear magnetic resonance (NMR) spectroscopy elemental analyzers. They were analyzed using impedance spectroscopy in the frequency range of 100Hz-1 MHz. LI and L2 showed higher conductivity compared to their metal complexes, which had values of 1.3 7 x 10-7 and 6.13 x 10-8 S/cm respectively. 

Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

2019 ◽  
Author(s):  
Swaraj Sengupta ◽  
Sahanwaj Khan ◽  
Shyamal K. Chattopadhyay ◽  
Indrani Banerjee ◽  
Tarun K. Panda ◽  
...  
Keyword(s):  
Schiff Base ◽  
Single Crystal ◽  
Copper Complex ◽  
Carbonyl Compounds ◽  
Nickel Complex ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Phenoxazinone Synthase ◽  
Catecholase Activity ◽  
Aromatic Carbonyl Compounds

Synthesis and characterisation of one trinuclear copper complex, ([Cu<sub>3</sub>L<sub>3</sub>O]ClO<sub>4</sub>) (<b>1</b>) and one nickel complex ([Ni(L'H)<sub>2</sub>(dmso)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>) (<b>2</b>) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L<sup>'</sup>H). <b>1</b> shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. <b>2 </b> shows phenoxazinone synthase activity.

Sign in / Sign up

Export Citation Format

Share Document