Electron Paramagnetic Resonance Study of a Langmuir−Blodgett Film of Manganese Octadecylphosphonate and Comparison of the Magnetic Properties to Those of Solid-State Manganese Alkylphosphonates

1996 ◽  
Vol 35 (12) ◽  
pp. 3479-3483 ◽  
Author(s):  
Candace T. Seip ◽  
Houston Byrd ◽  
Daniel R. Talham
Photonics ◽  
2019 ◽  
Vol 6 (4) ◽  
pp. 107
Author(s):  
Yuriy G. Galyametdinov ◽  
Dmitriy O. Sagdeev ◽  
Andrey A. Sukhanov ◽  
Violeta K. Voronkova ◽  
Radik R. Shamilov

Synthesis of nanoparticles doped with various ions can significantly expand their functionality. The conditions of synthesis exert significant influence on the distribution nature of doped ions and therefore the physicochemical properties of nanoparticles. In this paper, a correlation between the conditions of synthesis of manganese-containing cadmium sulfide or zinc sulfide nanoparticles and their optical and magnetic properties is analyzed. Electron paramagnetic resonance was used to study the distribution of manganese ions in nanoparticles and the intensity of interaction between them depending on the conditions of synthesis of nanoparticles, the concentration of manganese, and the type of initial semiconductor. The increase of manganese concentration is shown to result in the formation of smaller CdS-based nanoparticles. Luminescent properties of nanoparticles were studied. The 580 nm peak, which is typical for manganese ions, becomes more distinguished with the increase of their concentration and the time of synthesis.


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