First Mixed Fluoro−Chloro Group 4 Organometallics:  Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me5)4Hf4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF]

Eamonn F. Murphy; Thomas Lübben; Axel Herzog; Herbert W. Roesky; Alojz Demsar; Mathias Noltemeyer; Hans-Georg Schmidt

doi:10.1021/ic950822a

First Mixed Fluoro−Chloro Group 4 Organometallics: Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me5)4Hf4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF]

Inorganic Chemistry ◽

10.1021/ic950822a ◽

1996 ◽

Vol 35 (1) ◽

pp. 23-29 ◽

Cited By ~ 11

Author(s):

Eamonn F. Murphy ◽

Thomas Lübben ◽

Axel Herzog ◽

Herbert W. Roesky ◽

Alojz Demsar ◽

...

Keyword(s):

Structural Characterization ◽

Group 4 ◽

Chloro Group

Download Full-text

New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Organometallics ◽

10.1021/om0701569 ◽

2007 ◽

Vol 26 (14) ◽

pp. 3374-3384 ◽

Cited By ~ 33

Author(s):

Jong-Dae Lee ◽

Young-Joo Lee ◽

Ki-Chul Son ◽

Minserk Cheong ◽

Jaejung Ko ◽

...

Keyword(s):

Metal Complexes ◽

Structural Characterization ◽

System Synthesis ◽

Ligand System ◽

Group 4 ◽

Constrained Geometry ◽

Group 4 Metal

Download Full-text

Structural characterization of Group 4 transition metal halide bis-Arduengo carbene complexes MCl4L2:

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(02)01731-x ◽

2002 ◽

Vol 663 (1-2) ◽

pp. 192-203 ◽

Cited By ~ 44

Author(s):

Martin Niehues ◽

Gerald Kehr ◽

Gerhard Erker ◽

Birgit Wibbeling ◽

Roland Fröhlich ◽

...

Keyword(s):

Transition Metal ◽

Structural Characterization ◽

Metal Halide ◽

Carbene Complexes ◽

Group 4

Download Full-text

Halo carbonyls of the group 4 elements. Synthesis and structural characterization of Hf(CO)2(Me2PCH2CH2PMe2)2I2, the first stable derivative of the unknown Hf(CO)6I2

Organometallics ◽

10.1021/om00161a004 ◽

1990 ◽

Vol 9 (11) ◽

pp. 2858-2859 ◽

Cited By ~ 4

Author(s):

John E. Ellis ◽

Scott R. Frerichs ◽

Kai Ming Chi

Keyword(s):

Structural Characterization ◽

Group 4

Download Full-text

Application of Amine Elimination for the Efficient Preparation of Electrophilicansa-Monocyclopentadienyl Group 4 Complexes Containing an Appended Amido Functionality. Structural Characterization of [(C5H4)SiMe2(N-t-Bu)]ZrCl2(NMe2H).

Organometallics ◽

10.1021/om9603023 ◽

1996 ◽

Vol 15 (11) ◽

pp. 2668-2668 ◽

Cited By ~ 3

Author(s):

Donald W. Carpenetti ◽

Lioba Kloppenburg ◽

Justin T. Kupec ◽

Jeffrey L. Petersen

Keyword(s):

Structural Characterization ◽

Group 4

Download Full-text

A New Synthetic Route to High-Valent Half-Sandwich Group 4 Metallacarborane Alkyls. Synthesis and Structural Characterization of [η1:η6-(Me2NCH2CH2)C2B10H11]Hf(CH2SiMe3)2

Organometallics ◽

10.1021/om050290y ◽

2005 ◽

Vol 24 (13) ◽

pp. 3037-3039 ◽

Cited By ~ 8

Author(s):

Mak-Shuen Cheung ◽

Hoi-Shan Chan ◽

Zuowei Xie

Keyword(s):

Structural Characterization ◽

Synthetic Route ◽

Group 4 ◽

High Valent ◽

Half Sandwich

Download Full-text

Synthesis and Structural Characterization of Group 4 Metal Alkoxide Complexes of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine and Their Use As Initiators in the Ring-Opening Polymerization (ROP) of rac-Lactide under Industrially Relevant Conditions

Inorganic Chemistry ◽

10.1021/ic400667z ◽

2013 ◽

Vol 52 (19) ◽

pp. 10804-10811 ◽

Cited By ~ 27

Author(s):

Christopher J. Chuck ◽

Matthew G. Davidson ◽

Gerrit Gobius du Sart ◽

Petya K. Ivanova-Mitseva ◽

Gabriele I. Kociok-Köhn ◽

...

Keyword(s):

Structural Characterization ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Metal Alkoxide ◽

Group 4 ◽

Group 4 Metal

Download Full-text

ChemInform Abstract: Oxygen-Atom Transfer from Nitrous Oxide. Identification of Intermediates in the Oxidation of Diphenylacetylene at Group 4 Metal Centers and the Structural Characterization of (η-C5Me5)2Ti(N(O)NCPh=CPh)·1/2 C7H8.

ChemInform ◽

10.1002/chin.198941254 ◽

1989 ◽

Vol 20 (41) ◽

Author(s):

G. A. VAUGHAN ◽

C. D. SOFIELD ◽

G. L. HILLHOUSE ◽

A. L. RHEINGOLD

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Structural Characterization ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Metal Centers ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis and Structural Characterization of Group 4 Metal Carboxylates for Nanowire Production

Inorganic Chemistry ◽

10.1021/ic501904m ◽

2014 ◽

Vol 53 (23) ◽

pp. 12449-12458 ◽

Cited By ~ 6

Author(s):

Timothy J. Boyle ◽

Daniel T. Yonemoto ◽

Thu Q. Doan ◽

Todd M. Alam

Keyword(s):

Structural Characterization ◽

Metal Carboxylates ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Oxygen-atom transfer from nitrous oxide. Identification of intermediates in the oxidation of diphenylacetylene at Group 4 metal centers and the structural characterization of (.eta.-C5Me5)2Ti{N(O)NCPh:CPh}.cntdot.1/2C7H8

Journal of the American Chemical Society ◽

10.1021/ja00196a080 ◽

1989 ◽

Vol 111 (14) ◽

pp. 5491-5493 ◽

Cited By ~ 41

Author(s):

G. Alan Vaughan ◽

Chadwick D. Sofield ◽

Gregory L. Hillhouse ◽

Arnold L. Rheingold

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Structural Characterization ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Metal Centers ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis, spectroscopic and structural characterization of the first mixed fluoro-bromo group 4 organometallic complex [{CpZrF2Br}4] (Cp = C5Me5)

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.19966220332 ◽

1996 ◽

Vol 622 (3) ◽

pp. 579-582 ◽

Cited By ~ 3

Author(s):

Eamonn F. Murphy ◽

Ramaswamy Murugavel ◽

Herbert W. Roesky ◽

Mathias Noltemeyer ◽

Hans-Georg Schmidt

Keyword(s):

Structural Characterization ◽

Organometallic Complex ◽

Group 4

Download Full-text

First Mixed Fluoro−Chloro Group 4 Organometallics: Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me5)4Hf4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF]

New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Structural characterization of Group 4 transition metal halide bis-Arduengo carbene complexes MCl4L2:

Halo carbonyls of the group 4 elements. Synthesis and structural characterization of Hf(CO)2(Me2PCH2CH2PMe2)2I2, the first stable derivative of the unknown Hf(CO)6I2

Application of Amine Elimination for the Efficient Preparation of Electrophilicansa-Monocyclopentadienyl Group 4 Complexes Containing an Appended Amido Functionality. Structural Characterization of [(C5H4)SiMe2(N-t-Bu)]ZrCl2(NMe2H).

A New Synthetic Route to High-Valent Half-Sandwich Group 4 Metallacarborane Alkyls. Synthesis and Structural Characterization of [η1:η6-(Me2NCH2CH2)C2B10H11]Hf(CH2SiMe3)2

Synthesis and Structural Characterization of Group 4 Metal Alkoxide Complexes of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine and Their Use As Initiators in the Ring-Opening Polymerization (ROP) of rac-Lactide under Industrially Relevant Conditions

ChemInform Abstract: Oxygen-Atom Transfer from Nitrous Oxide. Identification of Intermediates in the Oxidation of Diphenylacetylene at Group 4 Metal Centers and the Structural Characterization of (η-C5Me5)2Ti(N(O)NCPh=CPh)·1/2 C7H8.

Synthesis and Structural Characterization of Group 4 Metal Carboxylates for Nanowire Production

Oxygen-atom transfer from nitrous oxide. Identification of intermediates in the oxidation of diphenylacetylene at Group 4 metal centers and the structural characterization of (.eta.-C5Me5)2Ti{N(O)NCPh:CPh}.cntdot.1/2C7H8

Synthesis, spectroscopic and structural characterization of the first mixed fluoro-bromo group 4 organometallic complex [{Cp*ZrF2Br}4] (Cp* = C5Me5)

Synthesis, spectroscopic and structural characterization of the first mixed fluoro-bromo group 4 organometallic complex [{CpZrF2Br}4] (Cp = C5Me5)