Heavy Alkali Metal Amides: Role of Secondary Interactions in Metal Stabilization

2009 ◽  
Vol 48 (23) ◽  
pp. 11459-11465 ◽  
Author(s):  
Ana Torvisco ◽  
Katharina Decker ◽  
Frank Uhlig ◽  
Karin Ruhlandt-Senge
Keyword(s):  
Alkali Metal ◽  
Metal Amides ◽  
Secondary Interactions ◽  
Metal Stabilization

Exploring secondary interactions and the role of temperature in moisture-contaminated polymer networks through molecular simulations

Soft Matter ◽  
2021 ◽  
Vol 17 (10) ◽  
pp. 2942-2956
Author(s):  
Rishabh D. Guha ◽  
Ogheneovo Idolor ◽  
Katherine Berkowitz ◽  
Melissa Pasquinelli ◽  
Landon R. Grace
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulations ◽  
Temperature Variation ◽  
Polymer Networks ◽  
Molecular Simulations ◽  
Effect Of Temperature ◽  
Secondary Interactions ◽  
Dynamics Simulations ◽  
Secondary Bonding

We investigated the effect of temperature variation on the secondary bonding interactions between absorbed moisture and epoxies with different morphologies using molecular dynamics simulations.

scholarly journals Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides

Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1013
Author(s):  
Stefanie Gärtner
Keyword(s):  
Crystal Structure ◽  
Alkali Metal ◽  
Crystal Structures ◽  
Alkali Metals ◽  
Valence Electron ◽  
Oxidation States ◽  
Valence Electron Concentration ◽  
Base Metals ◽  
Charge Balancing

Alkali metal thallides go back to the investigative works of Eduard Zintl about base metals in negative oxidation states. In 1932, he described the crystal structure of NaTl as the first representative for this class of compounds. Since then, a bunch of versatile crystal structures has been reported for thallium as electronegative element in intermetallic solid state compounds. For combinations of thallium with alkali metals as electropositive counterparts, a broad range of different unique structure types has been observed. Interestingly, various thallium substructures at the same or very similar valence electron concentration (VEC) are obtained. This in return emphasizes that the role of the alkali metals on structure formation goes far beyond ancillary filling atoms, which are present only due to charge balancing reasons. In this review, the alkali metals are in focus and the local surroundings of the latter are discussed in terms of their crystallographic sites in the corresponding crystal structures.

σ-Silane Ruthenium Complexes: The Crucial Role of Secondary Interactions

2006 ◽  
Vol 2006 (11) ◽  
pp. 2115-2127 ◽  
Author(s):  
Sébastien Lachaize ◽  
Sylviane Sabo-Etienne
Keyword(s):  
Crucial Role ◽  
Ruthenium Complexes ◽  
Secondary Interactions

Thermally Induced Electron Transfer in a CsCoFe Prussian Blue Derivative: The Specific Role of the Alkali-Metal Ion

2004 ◽  
Vol 116 (28) ◽  
pp. 3814-3817 ◽  
Author(s):  
Anne Bleuzen ◽  
Virginie Escax ◽  
Alban Ferrier ◽  
Françoise Villain ◽  
Michel Verdaguer ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Prussian Blue ◽  
Metal Ion ◽  
Specific Role ◽  
Alkali Metal Ion ◽  
Thermally Induced

One-dimensional cadmium(II)/bicinate(−1) complexes : The role of the alkali metal ion used in the reaction medium

Polyhedron ◽  
2011 ◽  
Vol 30 (2) ◽  
pp. 397-404 ◽  
Author(s):  
Eugenia Katsoulakou ◽  
Konstantis F. Konidaris ◽  
Aris Terzis ◽  
Catherine P. Raptopoulou ◽  
Spyros P. Perlepes ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Ion ◽  
Reaction Medium ◽  
Alkali Metal Ion ◽  
One Dimensional

The role of alkali metal sulphates in the oxidation of naphthalene to phthalic anhydride

1982 ◽  
Vol 3 (2) ◽  
pp. 151-160 ◽  
Author(s):  
D.W.B. Westerman ◽  
N.R. Foster ◽  
M.S. Wainwright
Keyword(s):  
Alkali Metal ◽  
Phthalic Anhydride ◽  
Metal Sulphates

The Role of Secondary Interactions in Selective Electrostatic Multilayer Deposition

Langmuir ◽  
2000 ◽  
Vol 16 (26) ◽  
pp. 10206-10214 ◽  
Author(s):  
Sarah L. Clark ◽  
Paula T. Hammond
Keyword(s):  
Multilayer Deposition ◽  
Secondary Interactions
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